Correlation between CH(A) and H+ produced by dissociative ionization of ethylene

Kenji Furuya, Eri Koto, Takeshi Ueda, Kouichiro Maruyama, Teiichiro Ogawa

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Dissociative ionization of ethylene by controlled electron impact has been investigated using a new fragment ion-photon coincidence apparatus. There is a clear correlation between the CH(A-X) emission and H+ production. The H+ band shape in the spectrum is simulated well, based on the CH(A-X) emission lifetime and H+ translational energy. An average translational energy of H+ is estimated to be about 0.1 eV. This small value implies sequential dissociation of the parent ion and/or dissociation from a doubly excited state.

Original languageEnglish
Pages (from-to)816-820
Number of pages5
JournalChemical Physics Letters
Volume288
Issue number5-6
DOIs
Publication statusPublished - May 29 1998

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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