Correlation of reaction rate constants for isoprene and maleic anhydride in mixed solvents

Haruo Kato; Yu Ito; Setsuko Yonezawa; Katsumi Honda; Yasuhiko Arai

doi:10.5188/jsmerj.17.39

Correlation of reaction rate constants for isoprene and maleic anhydride in mixed solvents

Haruo Kato, Yu Ito, Setsuko Yonezawa, Katsumi Honda, Yasuhiko Arai

Molecular and Biochemical Systems Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A correlative method for determination of reaction rate constants in mixed solvents system previously proposed was applied for Diels-Alder reaction of isoprene-maleic anhydride. In this study, several binary mixed solvents such as hexane, toluene, ethyl acetate and monochlorobenzene with nitrobenzene were examined. By adjusting the model parameters for the excess activation energy, the relationship between rate constants and compositions of mixed solvents used were well explained. The excess activation energy was compared with the excess Gibbs energy predicted by an activity-coefficient equation.

Original language	English
Pages (from-to)	39-41
Number of pages	3
Journal	International Journal of the Society of Material Engineering for Resources
Volume	17
Issue number	2
DOIs	https://doi.org/10.5188/jsmerj.17.39
Publication status	Published - Feb 2005

All Science Journal Classification (ASJC) codes

Chemical Engineering(all)
Materials Science(all)
Mechanical Engineering

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AU - Kato, Haruo

AU - Ito, Yu

AU - Yonezawa, Setsuko

AU - Honda, Katsumi

AU - Arai, Yasuhiko

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AB - A correlative method for determination of reaction rate constants in mixed solvents system previously proposed was applied for Diels-Alder reaction of isoprene-maleic anhydride. In this study, several binary mixed solvents such as hexane, toluene, ethyl acetate and monochlorobenzene with nitrobenzene were examined. By adjusting the model parameters for the excess activation energy, the relationship between rate constants and compositions of mixed solvents used were well explained. The excess activation energy was compared with the excess Gibbs energy predicted by an activity-coefficient equation.

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