Abstract
A correlative method for determination of reaction rate constants in mixed solvents system previously proposed was applied for Diels-Alder reaction of isoprene-maleic anhydride. In this study, several binary mixed solvents such as hexane, toluene, ethyl acetate and monochlorobenzene with nitrobenzene were examined. By adjusting the model parameters for the excess activation energy, the relationship between rate constants and compositions of mixed solvents used were well explained. The excess activation energy was compared with the excess Gibbs energy predicted by an activity-coefficient equation.
| Original language | English |
|---|---|
| Pages (from-to) | 39-41 |
| Number of pages | 3 |
| Journal | International Journal of the Society of Material Engineering for Resources |
| Volume | 17 |
| Issue number | 2 |
| Publication status | Published - Feb 1 2005 |
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All Science Journal Classification (ASJC) codes
- Chemical Engineering(all)
- Materials Science(all)
- Mechanical Engineering
Cite this
Correlation of reaction rate constants for isoprene and maleic anhydride in mixed solvents. / Kato, Haruo; Ito, Yu; Yonezawa, Setsuko; Honda, Katsumi; Arai, Yasuhiko.
In: International Journal of the Society of Material Engineering for Resources, Vol. 17, No. 2, 01.02.2005, p. 39-41.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Correlation of reaction rate constants for isoprene and maleic anhydride in mixed solvents
AU - Kato, Haruo
AU - Ito, Yu
AU - Yonezawa, Setsuko
AU - Honda, Katsumi
AU - Arai, Yasuhiko
PY - 2005/2/1
Y1 - 2005/2/1
N2 - A correlative method for determination of reaction rate constants in mixed solvents system previously proposed was applied for Diels-Alder reaction of isoprene-maleic anhydride. In this study, several binary mixed solvents such as hexane, toluene, ethyl acetate and monochlorobenzene with nitrobenzene were examined. By adjusting the model parameters for the excess activation energy, the relationship between rate constants and compositions of mixed solvents used were well explained. The excess activation energy was compared with the excess Gibbs energy predicted by an activity-coefficient equation.
AB - A correlative method for determination of reaction rate constants in mixed solvents system previously proposed was applied for Diels-Alder reaction of isoprene-maleic anhydride. In this study, several binary mixed solvents such as hexane, toluene, ethyl acetate and monochlorobenzene with nitrobenzene were examined. By adjusting the model parameters for the excess activation energy, the relationship between rate constants and compositions of mixed solvents used were well explained. The excess activation energy was compared with the excess Gibbs energy predicted by an activity-coefficient equation.
UR - http://www.scopus.com/inward/record.url?scp=33746044138&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33746044138&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:33746044138
VL - 17
SP - 39
EP - 41
JO - International Journal of the Society of Materials Engineering for Resources
JF - International Journal of the Society of Materials Engineering for Resources
SN - 1347-9725
IS - 2
ER -