Correlation of reaction rate constants for isoprene and maleic anhydride in mixed solvents

Haruo Kato, Yu Ito, Setsuko Yonezawa, Katsumi Honda, Yasuhiko Arai

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A correlative method for determination of reaction rate constants in mixed solvents system previously proposed was applied for Diels-Alder reaction of isoprene-maleic anhydride. In this study, several binary mixed solvents such as hexane, toluene, ethyl acetate and monochlorobenzene with nitrobenzene were examined. By adjusting the model parameters for the excess activation energy, the relationship between rate constants and compositions of mixed solvents used were well explained. The excess activation energy was compared with the excess Gibbs energy predicted by an activity-coefficient equation.

Original languageEnglish
Pages (from-to)39-41
Number of pages3
JournalInternational Journal of the Society of Material Engineering for Resources
Volume17
Issue number2
Publication statusPublished - Feb 1 2005

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Maleic Anhydrides
Isoprene
Maleic anhydride
Reaction rates
Rate constants
Activation energy
Nitrobenzene
Activity coefficients
Toluene
Hexanes
Gibbs free energy
Hexane
Chemical analysis
isoprene

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Materials Science(all)
  • Mechanical Engineering

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Correlation of reaction rate constants for isoprene and maleic anhydride in mixed solvents. / Kato, Haruo; Ito, Yu; Yonezawa, Setsuko; Honda, Katsumi; Arai, Yasuhiko.

In: International Journal of the Society of Material Engineering for Resources, Vol. 17, No. 2, 01.02.2005, p. 39-41.

Research output: Contribution to journalArticle

Kato, Haruo ; Ito, Yu ; Yonezawa, Setsuko ; Honda, Katsumi ; Arai, Yasuhiko. / Correlation of reaction rate constants for isoprene and maleic anhydride in mixed solvents. In: International Journal of the Society of Material Engineering for Resources. 2005 ; Vol. 17, No. 2. pp. 39-41.
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