Abstract
A correlative method for determination of reaction rate constants in mixed solvents system previously proposed was applied for Diels-Alder reaction of isoprene-maleic anhydride. In this study, several binary mixed solvents such as hexane, toluene, ethyl acetate and monochlorobenzene with nitrobenzene were examined. By adjusting the model parameters for the excess activation energy, the relationship between rate constants and compositions of mixed solvents used were well explained. The excess activation energy was compared with the excess Gibbs energy predicted by an activity-coefficient equation.
| Original language | English |
|---|---|
| Pages (from-to) | 39-41 |
| Number of pages | 3 |
| Journal | International Journal of the Society of Material Engineering for Resources |
| Volume | 17 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Feb 2005 |
All Science Journal Classification (ASJC) codes
- Chemical Engineering(all)
- Materials Science(all)
- Mechanical Engineering
Fingerprint Dive into the research topics of 'Correlation of reaction rate constants for isoprene and maleic anhydride in mixed solvents'. Together they form a unique fingerprint.
Cite this
Kato, H., Ito, Y., Yonezawa, S., Honda, K., & Arai, Y. (2005). Correlation of reaction rate constants for isoprene and maleic anhydride in mixed solvents. International Journal of the Society of Material Engineering for Resources, 17(2), 39-41. https://doi.org/10.5188/jsmerj.17.39