CORRELATION OF VAPOR-LIQUID EQUILIBRIA OF ETHANOL-WATER-CALCIUM CHLORIDE AND METHANOL-ETHANOL-CALCIUM CHLORIDE SYSTEMS AT 25 degree C.

Kenji Mishima, Yoshio Iwai, Sojuro Yamaguchi, Hidenori Isonaga, Yasuhiko Arai, Masaru Hongo

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

There is often a large change in the volatility of a liquid mixture caused by electrolyte compounds. The volatility is enhanced (salting-out) or reduced (salting-in) owing to the characteristic of solutions. Utilizing the salting-out effect, one can separate an azeotropic mixture such as the ethanol-water mixture from the fermentation of biomass. In the present study, the correlation performance of the ASOG model coupled with solvation and electrostatic contributions previously proposed, the empirical approach of Hala, and the local composition model of Chen et al. were discussed by applying the three models to correlate the vapor-liquid equilibria.

Original languageEnglish
Pages (from-to)407-433
Number of pages27
JournalMemoirs of the Faculty of Engineering, Kyushu University
Volume46
Issue number4
Publication statusPublished - Dec 1986

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Calcium chloride
Phase equilibria
methanol
ethanol
Methanol
Ethanol
calcium
chloride
liquid
Water
Solvation
water
Fermentation
electrolyte
fermentation
Electrostatics
Biomass
Electrolytes
biomass
Liquids

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

CORRELATION OF VAPOR-LIQUID EQUILIBRIA OF ETHANOL-WATER-CALCIUM CHLORIDE AND METHANOL-ETHANOL-CALCIUM CHLORIDE SYSTEMS AT 25 degree C. / Mishima, Kenji; Iwai, Yoshio; Yamaguchi, Sojuro; Isonaga, Hidenori; Arai, Yasuhiko; Hongo, Masaru.

In: Memoirs of the Faculty of Engineering, Kyushu University, Vol. 46, No. 4, 12.1986, p. 407-433.

Research output: Contribution to journalArticle

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