Abstract
Two new porphycenes functionalized with ferrocenyl pendants have been synthesized and characterized spectroscopically and structurally. The porphycene-based emission in porphycene-ferrocene dyads was switched on and off by the reversible control of the ferrocenyl pendant redox states. Transient absorption spectroscopy with a femtosecond laser-pulsed technique has successfully detected the picosecond charge-separated excited state of the dyad upon Q-band excitation of the porphycene ring.
| Original language | English |
|---|---|
| Pages (from-to) | 7-9 |
| Number of pages | 3 |
| Journal | Inorganic chemistry |
| Volume | 55 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 4 2016 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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Abe, M., Yamada, H., Okawara, T., Fujitsuka, M., Majima, T., & Hisaeda, Y. (2016). Covalently Attached Porphycene-Ferrocene Dyads: Synthesis, Redox-Switched Emission, and Observation of the Charge-Separated State. Inorganic chemistry, 55(1), 7-9. https://doi.org/10.1021/acs.inorgchem.5b02078