@article{4b9ce7d906a14b578096b9647cfaee0d,
title = "Covalently Attached Porphycene-Ferrocene Dyads: Synthesis, Redox-Switched Emission, and Observation of the Charge-Separated State",
abstract = "Two new porphycenes functionalized with ferrocenyl pendants have been synthesized and characterized spectroscopically and structurally. The porphycene-based emission in porphycene-ferrocene dyads was switched on and off by the reversible control of the ferrocenyl pendant redox states. Transient absorption spectroscopy with a femtosecond laser-pulsed technique has successfully detected the picosecond charge-separated excited state of the dyad upon Q-band excitation of the porphycene ring.",
author = "Masaaki Abe and Hiroaki Yamada and Toru Okawara and Mamoru Fujitsuka and Tetsuro Majima and Yoshio Hisaeda",
note = "Funding Information: We appreciate financial support from Grants-in-Aid for Scientific Research on Innovative Areas {"}Stimuli-responsive Chemical Species for the Creation of Functional Molecules{"} (Grant 15H00952) and {"}Coordination Programming{"} (Grant 24108730), Grants-in-Aid for Scientific Research (A) (Grant 21245016) and (B) (Grant 25288031), the Global COE Program {"}Science for Future Molecular Systems{"}, and the Nanotechnology Platform (Grant NPS13103) from MEXT. M.A. also acknowledges financial support from the Tokuyama Science Foundation. Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",
year = "2016",
month = jan,
day = "4",
doi = "10.1021/acs.inorgchem.5b02078",
language = "English",
volume = "55",
pages = "7--9",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "1",
}