Critical parameters and saturated densities in the critical region for trans -1,3,3,3-Tetrafluoropropene (HFO-1234ze(E))

Yukihiro Higashi, Katsuyuki Tanaka, Tomohide Ichikawa

Research output: Contribution to journalArticle

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Abstract

Measurements of the saturated vapor and liquid densities near the critical point for trans-1,3,3,3-tetrafluoropropene (CFH=CHCF3; HFO-1234ze(E)) were carried out in the reduced temperature range of 0.962 < T/Tc < 1 and in the reduced density range of 0.40 < ρ/ρc < 1.70. Taking into consideration the meniscus disappearing level as well as the intensity of the critical opalescence, the critical temperature T c and critical density ρc were determined experimentally. The critical pressure Pc was calculated by extrapolating the vapor-pressure equation to the critical temperature. The critical parameters reported in this paper are Tc = (382.51 ± 0.01) K, ρc = (486 ± 3) kgm-3, Vc = (235 ± 2) cm3mol-1, and Pc = (3632 ± 3) kPa. The saturated liquid density correlation is formulated using the present data. In addition, the critical exponent β along the coexistence curve was also discussed.

Original languageEnglish
Pages (from-to)1594-1597
Number of pages4
JournalJournal of Chemical and Engineering Data
Volume55
Issue number4
DOIs
Publication statusPublished - Apr 8 2010
Externally publishedYes

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Density of liquids
Density of gases
Vapor pressure
Temperature
1,3,3,3-tetrafluoropropene

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Critical parameters and saturated densities in the critical region for trans -1,3,3,3-Tetrafluoropropene (HFO-1234ze(E)). / Higashi, Yukihiro; Tanaka, Katsuyuki; Ichikawa, Tomohide.

In: Journal of Chemical and Engineering Data, Vol. 55, No. 4, 08.04.2010, p. 1594-1597.

Research output: Contribution to journalArticle

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AU - Tanaka, Katsuyuki

AU - Ichikawa, Tomohide

PY - 2010/4/8

Y1 - 2010/4/8

N2 - Measurements of the saturated vapor and liquid densities near the critical point for trans-1,3,3,3-tetrafluoropropene (CFH=CHCF3; HFO-1234ze(E)) were carried out in the reduced temperature range of 0.962 < T/Tc < 1 and in the reduced density range of 0.40 < ρ/ρc < 1.70. Taking into consideration the meniscus disappearing level as well as the intensity of the critical opalescence, the critical temperature T c and critical density ρc were determined experimentally. The critical pressure Pc was calculated by extrapolating the vapor-pressure equation to the critical temperature. The critical parameters reported in this paper are Tc = (382.51 ± 0.01) K, ρc = (486 ± 3) kgm-3, Vc = (235 ± 2) cm3mol-1, and Pc = (3632 ± 3) kPa. The saturated liquid density correlation is formulated using the present data. In addition, the critical exponent β along the coexistence curve was also discussed.

AB - Measurements of the saturated vapor and liquid densities near the critical point for trans-1,3,3,3-tetrafluoropropene (CFH=CHCF3; HFO-1234ze(E)) were carried out in the reduced temperature range of 0.962 < T/Tc < 1 and in the reduced density range of 0.40 < ρ/ρc < 1.70. Taking into consideration the meniscus disappearing level as well as the intensity of the critical opalescence, the critical temperature T c and critical density ρc were determined experimentally. The critical pressure Pc was calculated by extrapolating the vapor-pressure equation to the critical temperature. The critical parameters reported in this paper are Tc = (382.51 ± 0.01) K, ρc = (486 ± 3) kgm-3, Vc = (235 ± 2) cm3mol-1, and Pc = (3632 ± 3) kPa. The saturated liquid density correlation is formulated using the present data. In addition, the critical exponent β along the coexistence curve was also discussed.

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