Cross-coupling of benzylic acetates with arylboronic acids: One-pot transformation of benzylic alcohols to diarylmethanes

Ryoichi Kuwano; Masashi Yokogi

doi:10.1039/b513372f

Cross-coupling of benzylic acetates with arylboronic acids: One-pot transformation of benzylic alcohols to diarylmethanes

Ryoichi Kuwano, Masashi Yokogi

Multidisciplinary chemistry

Research output: Contribution to journal › Article › peer-review

81 Citations (Scopus)

Abstract

Benzylic acetates reacted with arylboronic acids in the presence of a DPEphos-[Pd(η³-C₃H₅)Cl]₂ catalyst when tert-amyl alcohol was used as a solvent, and the catalytic cross-couplings produced diarylmethanes in high yields (up to 94% isolated yield).

Original language	English
Pages (from-to)	5899-5901
Number of pages	3
Journal	Chemical Communications
Issue number	47
DOIs	https://doi.org/10.1039/b513372f
Publication status	Published - Dec 21 2005

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Cross-coupling of benzylic acetates with arylboronic acids: One-pot transformation of benzylic alcohols to diarylmethanes",

abstract = "Benzylic acetates reacted with arylboronic acids in the presence of a DPEphos-[Pd(η3-C3H5)Cl]2 catalyst when tert-amyl alcohol was used as a solvent, and the catalytic cross-couplings produced diarylmethanes in high yields (up to 94% isolated yield).",

author = "Ryoichi Kuwano and Masashi Yokogi",

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AU - Yokogi, Masashi

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Y1 - 2005/12/21

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AB - Benzylic acetates reacted with arylboronic acids in the presence of a DPEphos-[Pd(η3-C3H5)Cl]2 catalyst when tert-amyl alcohol was used as a solvent, and the catalytic cross-couplings produced diarylmethanes in high yields (up to 94% isolated yield).

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Cross-coupling of benzylic acetates with arylboronic acids: One-pot transformation of benzylic alcohols to diarylmethanes

Abstract

All Science Journal Classification (ASJC) codes

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