Crystal growth, defect structure and magnetism of new Li 3N-derived lithium nitridocobaltates

Alexandra G. Gordon, Ronald I. Smith, Claire Wilson, Zlatka Stoeva, Duncan H. Gregory

Research output: Contribution to journalArticle

Abstract

New nitridocobaltates Li3-x-yCoxN are revealed to contain significant Li+ vacancies (y ≈ 0.45) disordered within lithium-nitrogen planes and to exist as partially delocalised spin systems as a result of increased covalency through infinite -N-(Li,Co)-N- chains.

Original languageEnglish
Pages (from-to)2812-2813
Number of pages2
JournalChemical Communications
Issue number24
DOIs
Publication statusPublished - Dec 21 2004
Externally publishedYes

Fingerprint

Defect structures
Magnetism
Crystallization
Lithium
Crystal growth
Vacancies
Nitrogen

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Crystal growth, defect structure and magnetism of new Li 3N-derived lithium nitridocobaltates. / Gordon, Alexandra G.; Smith, Ronald I.; Wilson, Claire; Stoeva, Zlatka; Gregory, Duncan H.

In: Chemical Communications, No. 24, 21.12.2004, p. 2812-2813.

Research output: Contribution to journalArticle

Gordon, Alexandra G. ; Smith, Ronald I. ; Wilson, Claire ; Stoeva, Zlatka ; Gregory, Duncan H. / Crystal growth, defect structure and magnetism of new Li 3N-derived lithium nitridocobaltates. In: Chemical Communications. 2004 ; No. 24. pp. 2812-2813.
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