TY - JOUR
T1 - Crystal structure and photo-reaction of a new coordination polymer
T2 - [Ni(en) 2] 4[Fe(CN) 5NO] 2 [Fe(CN) 6]·6H 2O
AU - Gu, Zhong Ze
AU - Sato, Osamu
AU - Einaga, Yasuaki
AU - Kai, Masahiro
AU - Iyoda, Tomokazu
AU - Fujishima, Akira
AU - Hashimoto, Kazuhito
PY - 2001/9
Y1 - 2001/9
N2 - A new photo-responsive coordination polymer of [Ni(en) 2] 4[Fe(CN) 5NO] 2 [Fe(CN) 6]·6H 2O synthesized. In this compound, Ni-CN-Fe forms one-dimensional standing-wave-like chains, onto which photo-functional groups of pentacyanonitrosylferrate(II) are appended. Photo-irradiation with blue light at less than 200 K transformed the pentacyanonitrosylferrate(II) from the ground state to a metastable state, which could be reverted to the original state by irradiation with red light.
AB - A new photo-responsive coordination polymer of [Ni(en) 2] 4[Fe(CN) 5NO] 2 [Fe(CN) 6]·6H 2O synthesized. In this compound, Ni-CN-Fe forms one-dimensional standing-wave-like chains, onto which photo-functional groups of pentacyanonitrosylferrate(II) are appended. Photo-irradiation with blue light at less than 200 K transformed the pentacyanonitrosylferrate(II) from the ground state to a metastable state, which could be reverted to the original state by irradiation with red light.
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U2 - 10.1246/bcsj.74.1617
DO - 10.1246/bcsj.74.1617
M3 - Article
AN - SCOPUS:0034767862
SN - 0009-2673
VL - 74
SP - 1617
EP - 1622
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 9
ER -