Crystal structure and photo-reaction of a new coordination polymer

[Ni(en) 2] 4[Fe(CN) 5NO] 2 [Fe(CN) 6]·6H 2O

Zhong Ze Gu, Osamu Sato, Yasuaki Einaga, Masahiro Kai, Tomokazu Iyoda, Akira Fujishima, Kazuhito Hashimoto

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A new photo-responsive coordination polymer of [Ni(en) 2] 4[Fe(CN) 5NO] 2 [Fe(CN) 6]·6H 2O synthesized. In this compound, Ni-CN-Fe forms one-dimensional standing-wave-like chains, onto which photo-functional groups of pentacyanonitrosylferrate(II) are appended. Photo-irradiation with blue light at less than 200 K transformed the pentacyanonitrosylferrate(II) from the ground state to a metastable state, which could be reverted to the original state by irradiation with red light.

Original languageEnglish
Pages (from-to)1617-1622
Number of pages6
JournalBulletin of the Chemical Society of Japan
Volume74
Issue number9
DOIs
Publication statusPublished - Sep 1 2001
Externally publishedYes

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Polymers
Crystal structure
Irradiation
Ground state
Functional groups

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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Crystal structure and photo-reaction of a new coordination polymer : [Ni(en) 2] 4[Fe(CN) 5NO] 2 [Fe(CN) 6]·6H 2O. / Gu, Zhong Ze; Sato, Osamu; Einaga, Yasuaki; Kai, Masahiro; Iyoda, Tomokazu; Fujishima, Akira; Hashimoto, Kazuhito.

In: Bulletin of the Chemical Society of Japan, Vol. 74, No. 9, 01.09.2001, p. 1617-1622.

Research output: Contribution to journalArticle

Gu, Zhong Ze ; Sato, Osamu ; Einaga, Yasuaki ; Kai, Masahiro ; Iyoda, Tomokazu ; Fujishima, Akira ; Hashimoto, Kazuhito. / Crystal structure and photo-reaction of a new coordination polymer : [Ni(en) 2] 4[Fe(CN) 5NO] 2 [Fe(CN) 6]·6H 2O. In: Bulletin of the Chemical Society of Japan. 2001 ; Vol. 74, No. 9. pp. 1617-1622.
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