Crystal structure and thermal expansion of Ca2Y2Si2O9

H. Yamane, T. Nagasawa, Yasukazu Murakami, T. Kamata, D. Shindo, M. Shimada, Tadashi Endo

Research output: Contribution to journalArticle

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Abstract

The crystal structure of Ca2Y2Si2O9 was studied by X-ray and electron diffraction. Statistical atomic site positions were determined in an orthorhombic cell, a = 10.453(3), b = 3.720(2), c = 10.290(2) Å, space group Pnma. The local structure of Si2O7 silicate anions was illustrated from the refined atomic positions. The Ca2Y2Si2O9 structure could be explained by locally disordered arrangement of Y4Al2O9 monoclinic structure. The linear thermal expansion coefficient of Ca2Y2Si2O9 ceramics measured by dilatometry was 9.3 × 10-6 °C-1 from room temperature to 1500°C.

Original languageEnglish
Pages (from-to)845-853
Number of pages9
JournalMaterials Research Bulletin
Volume33
Issue number6
DOIs
Publication statusPublished - Jan 1 1998
Externally publishedYes

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Silicates
Electron diffraction
Thermal expansion
Anions
thermal expansion
Negative ions
Crystal structure
X ray diffraction
dilatometry
crystal structure
expansion
silicates
electron diffraction
ceramics
anions
Temperature
room temperature
coefficients
cells
diffraction

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Yamane, H., Nagasawa, T., Murakami, Y., Kamata, T., Shindo, D., Shimada, M., & Endo, T. (1998). Crystal structure and thermal expansion of Ca2Y2Si2O9 Materials Research Bulletin, 33(6), 845-853. https://doi.org/10.1016/S0025-5408(98)00059-2

Crystal structure and thermal expansion of Ca2Y2Si2O9 . / Yamane, H.; Nagasawa, T.; Murakami, Yasukazu; Kamata, T.; Shindo, D.; Shimada, M.; Endo, Tadashi.

In: Materials Research Bulletin, Vol. 33, No. 6, 01.01.1998, p. 845-853.

Research output: Contribution to journalArticle

Yamane, H, Nagasawa, T, Murakami, Y, Kamata, T, Shindo, D, Shimada, M & Endo, T 1998, 'Crystal structure and thermal expansion of Ca2Y2Si2O9 ', Materials Research Bulletin, vol. 33, no. 6, pp. 845-853. https://doi.org/10.1016/S0025-5408(98)00059-2
Yamane, H. ; Nagasawa, T. ; Murakami, Yasukazu ; Kamata, T. ; Shindo, D. ; Shimada, M. ; Endo, Tadashi. / Crystal structure and thermal expansion of Ca2Y2Si2O9 In: Materials Research Bulletin. 1998 ; Vol. 33, No. 6. pp. 845-853.
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AU - Shimada, M.

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