Crystal Structure of the Gold(III) Complex, Trichloro (dibenzyl sulfide) golo(III).

Kazuhiro Takahashi

doi:10.1246/bcsj.64.2572

Crystal Structure of the Gold(III) Complex, Trichloro (dibenzyl sulfide) golo(III).

Kazuhiro Takahashi

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of the title complex has been determined. The crystal is orthorhombic, with the space group Pnma, Z=4, a=13.331 (2), b=16.130 (3), and c=7.6949 (9) A. The complex has a square-planar coordination geometry. The Au and the 3C11S donor atoms are located on a crystallographic mirror plane. The length of the Au–Cl bond trans to the Au–S bond is slightly longer than those of the other two Au–Cl bonds.

Original language	English
Pages (from-to)	2572-2574
Number of pages	3
Journal	Bulletin of the Chemical Society of Japan
Volume	64
Issue number	8
DOIs	https://doi.org/10.1246/bcsj.64.2572
Publication status	Published - 1991

All Science Journal Classification (ASJC) codes

Chemistry(all)

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title = "Crystal Structure of the Gold(III) Complex, Trichloro (dibenzyl sulfide) golo(III).",

abstract = "The structure of the title complex has been determined. The crystal is orthorhombic, with the space group Pnma, Z=4, a=13.331 (2), b=16.130 (3), and c=7.6949 (9) A. The complex has a square-planar coordination geometry. The Au and the 3C11S donor atoms are located on a crystallographic mirror plane. The length of the Au–Cl bond trans to the Au–S bond is slightly longer than those of the other two Au–Cl bonds.",

author = "Kazuhiro Takahashi",

year = "1991",

doi = "10.1246/bcsj.64.2572",

language = "English",

volume = "64",

pages = "2572--2574",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "The Chemical Society of Japan",

number = "8",

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T1 - Crystal Structure of the Gold(III) Complex, Trichloro (dibenzyl sulfide) golo(III).

AU - Takahashi, Kazuhiro

PY - 1991

Y1 - 1991

N2 - The structure of the title complex has been determined. The crystal is orthorhombic, with the space group Pnma, Z=4, a=13.331 (2), b=16.130 (3), and c=7.6949 (9) A. The complex has a square-planar coordination geometry. The Au and the 3C11S donor atoms are located on a crystallographic mirror plane. The length of the Au–Cl bond trans to the Au–S bond is slightly longer than those of the other two Au–Cl bonds.

AB - The structure of the title complex has been determined. The crystal is orthorhombic, with the space group Pnma, Z=4, a=13.331 (2), b=16.130 (3), and c=7.6949 (9) A. The complex has a square-planar coordination geometry. The Au and the 3C11S donor atoms are located on a crystallographic mirror plane. The length of the Au–Cl bond trans to the Au–S bond is slightly longer than those of the other two Au–Cl bonds.

U2 - 10.1246/bcsj.64.2572

DO - 10.1246/bcsj.64.2572

M3 - Article

VL - 64

SP - 2572

EP - 2574

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

SN - 0009-2673

IS - 8

ER -