Crystal structures of palladium(II) and copper(II) complexes of meso-phenyl tripyrrinone

Hiroyuki Furuta, Hiromitsu Maeda, Atsuhiro Osuka

    Research output: Contribution to journalArticlepeer-review

    28 Citations (Scopus)

    Abstract

    Meso-phenyl tripyrrinone (2), which is derived directly from N-confused porphyrin by Cu(II)-assisted oxygenolysis, can serve as a metal coordination ligand using three nitrogens and one oxygen in the core. The crystal structures of Pd(II) and Cu(II) complexes show the similar square-planar N30-coordination but the mode of oligomeric chains formed in the crystals by π-π stacking interaction is different: zig-zag for Cu(II) and straight for Pd(II) complex.

    Original languageEnglish
    Pages (from-to)162-164
    Number of pages3
    JournalInorganic Chemistry Communications
    Volume6
    Issue number2
    DOIs
    Publication statusPublished - Feb 1 2003

    All Science Journal Classification (ASJC) codes

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

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