Crystal structures of palladium(II) and copper(II) complexes of meso-phenyl tripyrrinone

Hiroyuki Furuta, Hiromitsu Maeda, Atsuhiro Osuka

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Meso-phenyl tripyrrinone (2), which is derived directly from N-confused porphyrin by Cu(II)-assisted oxygenolysis, can serve as a metal coordination ligand using three nitrogens and one oxygen in the core. The crystal structures of Pd(II) and Cu(II) complexes show the similar square-planar N30-coordination but the mode of oligomeric chains formed in the crystals by π-π stacking interaction is different: zig-zag for Cu(II) and straight for Pd(II) complex.

Original languageEnglish
Pages (from-to)162-164
Number of pages3
JournalInorganic Chemistry Communications
Volume6
Issue number2
DOIs
Publication statusPublished - Feb 1 2003

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Porphyrins
Palladium
palladium
Copper
Nitrogen
Crystal structure
Metals
Ligands
Oxygen
copper
Crystals
crystal structure
porphyrins
nitrogen
ligands
oxygen
metals
crystals
interactions

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Crystal structures of palladium(II) and copper(II) complexes of meso-phenyl tripyrrinone. / Furuta, Hiroyuki; Maeda, Hiromitsu; Osuka, Atsuhiro.

In: Inorganic Chemistry Communications, Vol. 6, No. 2, 01.02.2003, p. 162-164.

Research output: Contribution to journalArticle

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AB - Meso-phenyl tripyrrinone (2), which is derived directly from N-confused porphyrin by Cu(II)-assisted oxygenolysis, can serve as a metal coordination ligand using three nitrogens and one oxygen in the core. The crystal structures of Pd(II) and Cu(II) complexes show the similar square-planar N30-coordination but the mode of oligomeric chains formed in the crystals by π-π stacking interaction is different: zig-zag for Cu(II) and straight for Pd(II) complex.

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