Crystalline assembly of metal-organic polyhedra driven by ionic interactions with polyoxometalates

Benjamin Le Ouay, Haruka Yoshino, Kenta Sasaki, Yuta Ohtsubo, Ryo Ohtani, Masaaki Ohba

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

Charge-driven self-assembly of cationic zirconium-based metal-organic polyhedra (MOPs) with polyoxometalates (POMs) leads to a series of porous crystalline salts, prepared by simple mixing of soluble precursors. The reactivity of immobilized POMs was greatly increased, as demonstrated by their fast reduction by hydrazine vapors, without loss of structural integrity.

Original languageEnglish
Pages (from-to)5187-5190
Number of pages4
JournalChemical Communications
Volume57
Issue number42
DOIs
Publication statusPublished - May 25 2021

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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