Current-Voltage Characteristics of Various Metal Electrodes in Limiting-Current-Type Zirconia Cells Application to Hydrocarbon Sensors

Takashi Takeuchi, Shingo Watanabe, Yoshiyasu Hatano, Miki Kuwano, Yukari Eguchi, Kazuaki Yoshida, Tatsumi Ishihara, Yusaku Takita

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The influence of electrode materials on the current vs. voltage characteristics of limiting-current-type zirconia cells has been investigated systematically. The cells have one or two pairs of electrodes consisting of Pt, Pd, Au, or Ag, and a cover with a pinhole, which serves to limit gas diffusion and, therefore, the electrical current of the cells. The limiting current was found to depend definitely on the catalytic activity of the electrodes for the oxidation reaction of hydrocarbon gases in oxygen and hydrocarbon-containing gases. The results were applied to improve the sensitivity of limiting-current hydrocarbon sensors. The highest sensitivity was attained for the following combination of electrodes: Pt and Ag inner electrodes and a Au outer electrode in two-inner-electrode sensors. A preliminary examination has also been made on a three-inner-electrode sensor.

Original languageEnglish
JournalJournal of the Electrochemical Society
Volume148
Issue number9
DOIs
Publication statusPublished - Sep 1 2001
Externally publishedYes

Fingerprint

Current voltage characteristics
Hydrocarbons
zirconium oxides
Zirconia
hydrocarbons
Metals
Electrodes
electrodes
sensors
Sensors
electric potential
cells
metals
Gases
gaseous diffusion
sensitivity
pinholes
electrode materials
zirconium oxide
Diffusion in gases

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Cite this

Current-Voltage Characteristics of Various Metal Electrodes in Limiting-Current-Type Zirconia Cells Application to Hydrocarbon Sensors. / Takeuchi, Takashi; Watanabe, Shingo; Hatano, Yoshiyasu; Kuwano, Miki; Eguchi, Yukari; Yoshida, Kazuaki; Ishihara, Tatsumi; Takita, Yusaku.

In: Journal of the Electrochemical Society, Vol. 148, No. 9, 01.09.2001.

Research output: Contribution to journalArticle

Takeuchi, Takashi ; Watanabe, Shingo ; Hatano, Yoshiyasu ; Kuwano, Miki ; Eguchi, Yukari ; Yoshida, Kazuaki ; Ishihara, Tatsumi ; Takita, Yusaku. / Current-Voltage Characteristics of Various Metal Electrodes in Limiting-Current-Type Zirconia Cells Application to Hydrocarbon Sensors. In: Journal of the Electrochemical Society. 2001 ; Vol. 148, No. 9.
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