Cyano-bridged one-dimensional Sm III-Fe III molecule-based magnet with an ordering temperature of 3.4 K

Chunhua Ge, Hui Zhong Kou, Zhong Hai Ni, Yun Bo Jiang, Li Fang Zhang, Ai Li Cui, Osamu Sato

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Abstract

A new cynao-bridged Sm III-Fe III bimetallic coordination polymer has been prepared by the reaction of (n-Bu 4N) 3Fe(CN) 6 and Sm(NO 3) 3·6H 2O in a DMF-H 2O media. The complex consists of alternate Sm(DMF) 4(H 2O) 2 and Fe(CN) 6 units bridged by two cis-cyano ligands to form a zigzag chain. It behaves as a molecule-based magnet with T c = 3.4 K. At 2 K, hysteresis was observed with a coercive field of 200 Oe.

Original languageEnglish
Article numberCL-050881
Pages (from-to)1280-1281
Number of pages2
JournalChemistry Letters
Volume34
Issue number9
DOIs
Publication statusPublished - Sep 5 2005

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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    Ge, C., Kou, H. Z., Ni, Z. H., Jiang, Y. B., Zhang, L. F., Cui, A. L., & Sato, O. (2005). Cyano-bridged one-dimensional Sm III-Fe III molecule-based magnet with an ordering temperature of 3.4 K. Chemistry Letters, 34(9), 1280-1281. [CL-050881]. https://doi.org/10.1246/cl.2005.1280