Cyano-bridged one-dimensional Sm III-Fe III molecule-based magnet with an ordering temperature of 3.4 K

Chunhua Ge, Hui Zhong Kou, Zhong Hai Ni, Yun Bo Jiang, Li Fang Zhang, Ai Li Cui, Osamu Sato

Research output: Contribution to journalArticle

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Abstract

A new cynao-bridged Sm III-Fe III bimetallic coordination polymer has been prepared by the reaction of (n-Bu 4N) 3Fe(CN) 6 and Sm(NO 3) 3·6H 2O in a DMF-H 2O media. The complex consists of alternate Sm(DMF) 4(H 2O) 2 and Fe(CN) 6 units bridged by two cis-cyano ligands to form a zigzag chain. It behaves as a molecule-based magnet with T c = 3.4 K. At 2 K, hysteresis was observed with a coercive field of 200 Oe.

Original languageEnglish
Article numberCL-050881
Pages (from-to)1280-1281
Number of pages2
JournalChemistry Letters
Volume34
Issue number9
DOIs
Publication statusPublished - Sep 5 2005

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Magnets
Hysteresis
Polymers
Ligands
Molecules
Temperature

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Ge, C., Kou, H. Z., Ni, Z. H., Jiang, Y. B., Zhang, L. F., Cui, A. L., & Sato, O. (2005). Cyano-bridged one-dimensional Sm III-Fe III molecule-based magnet with an ordering temperature of 3.4 K. Chemistry Letters, 34(9), 1280-1281. [CL-050881]. https://doi.org/10.1246/cl.2005.1280

Cyano-bridged one-dimensional Sm III-Fe III molecule-based magnet with an ordering temperature of 3.4 K. / Ge, Chunhua; Kou, Hui Zhong; Ni, Zhong Hai; Jiang, Yun Bo; Zhang, Li Fang; Cui, Ai Li; Sato, Osamu.

In: Chemistry Letters, Vol. 34, No. 9, CL-050881, 05.09.2005, p. 1280-1281.

Research output: Contribution to journalArticle

Ge, Chunhua ; Kou, Hui Zhong ; Ni, Zhong Hai ; Jiang, Yun Bo ; Zhang, Li Fang ; Cui, Ai Li ; Sato, Osamu. / Cyano-bridged one-dimensional Sm III-Fe III molecule-based magnet with an ordering temperature of 3.4 K. In: Chemistry Letters. 2005 ; Vol. 34, No. 9. pp. 1280-1281.
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