Cyano-containing quaternary ammonium-based ionic liquid as a 'co-solvent' for lithium battery electrolyte

Minato Egashira, Maika Nakagawa, Izumi Watanabe, Shigeto Okada, Jun Ichi Yamaki

Research output: Contribution to journalArticle

48 Citations (Scopus)

Abstract

Imidazolium-based ionic liquid is one of attractive candidates for advanced lithium battery electrolyte. However, its cathodic stability is not sufficient for the reversible charge-discharge of negative electrodes. The authors previously proposed a quaternary ammonium-based ionic liquid containing a cyano group (cyano-QA) as a film-forming electrolyte on the negative electrode surface. In the present study, several cyano-QA ionic liquids have been prepared and their electrolyte properties have been estimated. Some ionic liquids based on cyano-containing quaternary ammonium cation provided reversible lithium deposition/dissolution couple when they were used as 'co-solvent' of electrolyte with the co-existence of EMITFSI.

Original languageEnglish
Pages (from-to)685-688
Number of pages4
JournalJournal of Power Sources
Volume146
Issue number1-2
DOIs
Publication statusPublished - Aug 26 2005

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

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