Cyclodextrin-assisted synthesis of a metallosupramolecular terbium(III) polymer and its fluorescence properties and chiral recognition

Daisuke Yoshihara, Youichi Tsuchiya, Takao Noguchi, Tatsuhiro Yamamoto, Arnab Dawn, Seiji Shinkai

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

Hold and connect! Inclusion of a bridging ligand into cyclodextrin (CD), followed by the addition of TbIII leads to a polyrotaxane-type metallosupramolecular polymer (see figure, L=4,4′-biphenyldicarboxylic acid). This polymer can recognize chirality and differentiate enantiomers by fluorescence and circular dichroism spectral changes.

Original languageEnglish
Pages (from-to)15485-15488
Number of pages4
JournalChemistry - A European Journal
Volume19
Issue number46
DOIs
Publication statusPublished - Nov 11 2013

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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