Cyclodextrin-assisted synthesis of a metallosupramolecular terbium(III) polymer and its fluorescence properties and chiral recognition

Daisuke Yoshihara, Youichi Tsuchiya, Takao Noguchi, Tatsuhiro Yamamoto, Arnab Dawn, Seiji Shinkai

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Hold and connect! Inclusion of a bridging ligand into cyclodextrin (CD), followed by the addition of TbIII leads to a polyrotaxane-type metallosupramolecular polymer (see figure, L=4,4′-biphenyldicarboxylic acid). This polymer can recognize chirality and differentiate enantiomers by fluorescence and circular dichroism spectral changes.

Original languageEnglish
Pages (from-to)15485-15488
Number of pages4
JournalChemistry - A European Journal
Volume19
Issue number46
DOIs
Publication statusPublished - Nov 11 2013

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Terbium
Cyclodextrins
Polymers
Fluorescence
Enantiomers
Chirality
Dichroism
Ligands
Acids

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Cyclodextrin-assisted synthesis of a metallosupramolecular terbium(III) polymer and its fluorescence properties and chiral recognition. / Yoshihara, Daisuke; Tsuchiya, Youichi; Noguchi, Takao; Yamamoto, Tatsuhiro; Dawn, Arnab; Shinkai, Seiji.

In: Chemistry - A European Journal, Vol. 19, No. 46, 11.11.2013, p. 15485-15488.

Research output: Contribution to journalArticle

Yoshihara, Daisuke ; Tsuchiya, Youichi ; Noguchi, Takao ; Yamamoto, Tatsuhiro ; Dawn, Arnab ; Shinkai, Seiji. / Cyclodextrin-assisted synthesis of a metallosupramolecular terbium(III) polymer and its fluorescence properties and chiral recognition. In: Chemistry - A European Journal. 2013 ; Vol. 19, No. 46. pp. 15485-15488.
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