Decomposition of CCl2F2 over metal sulfate catalysts

Yusaku Takita, Jun Ichi Moriyama, Hiroyasu Nishiguchi, Tatsumi Ishihara, Fusakazu Hayano, Tetsuo Nakajo

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Activity for hydrolysis of CCl2F2 (CFC12) on various metal sulfate was investigated. Zr(SO4)2 was found to be the most active while FeSO4, Cr2(SO4) 3, Al2(SO4)3, La2(SO 4)3 and Ce2(SO4)3 had intermediate activity. MnSO4, CoSO4, and MgSO4 showed low activity and SrSO4, CaSO4, and BaSO 4 had even less activity. The major carbon containing product was CO2 and small amount of CClF3 and CO were formed over several sulfates. The crystal structure of the sulfates was stable during decomposition of CCl2F2, and the conversion reached a steady state after initial decrease at 275 °C over Zr(SO4) 2 catalyst. The concentration of surface hydroxyl was larger than that over AlPO4-based catalysts and a reaction mechanism similar to that over AlPO4-based catalysts was proposed.

Original languageEnglish
Pages (from-to)103-109
Number of pages7
JournalCatalysis Today
Volume88
Issue number3-4
DOIs
Publication statusPublished - Feb 15 2004
Externally publishedYes

Fingerprint

Sulfates
Metals
Decomposition
Catalysts
Carbon Monoxide
Hydroxyl Radical
Hydrolysis
Carbon
Crystal structure

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Takita, Y., Moriyama, J. I., Nishiguchi, H., Ishihara, T., Hayano, F., & Nakajo, T. (2004). Decomposition of CCl2F2 over metal sulfate catalysts. Catalysis Today, 88(3-4), 103-109. https://doi.org/10.1016/j.cattod.2003.11.003

Decomposition of CCl2F2 over metal sulfate catalysts. / Takita, Yusaku; Moriyama, Jun Ichi; Nishiguchi, Hiroyasu; Ishihara, Tatsumi; Hayano, Fusakazu; Nakajo, Tetsuo.

In: Catalysis Today, Vol. 88, No. 3-4, 15.02.2004, p. 103-109.

Research output: Contribution to journalArticle

Takita, Y, Moriyama, JI, Nishiguchi, H, Ishihara, T, Hayano, F & Nakajo, T 2004, 'Decomposition of CCl2F2 over metal sulfate catalysts', Catalysis Today, vol. 88, no. 3-4, pp. 103-109. https://doi.org/10.1016/j.cattod.2003.11.003
Takita Y, Moriyama JI, Nishiguchi H, Ishihara T, Hayano F, Nakajo T. Decomposition of CCl2F2 over metal sulfate catalysts. Catalysis Today. 2004 Feb 15;88(3-4):103-109. https://doi.org/10.1016/j.cattod.2003.11.003
Takita, Yusaku ; Moriyama, Jun Ichi ; Nishiguchi, Hiroyasu ; Ishihara, Tatsumi ; Hayano, Fusakazu ; Nakajo, Tetsuo. / Decomposition of CCl2F2 over metal sulfate catalysts. In: Catalysis Today. 2004 ; Vol. 88, No. 3-4. pp. 103-109.
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