Decomposition of environmentally persistent trifluoroacetic acid to fluoride ions by a homogeneous photocatalyst in water

Hisao Hori, Yuko Takano, Kazuhide Koike, Koji Takeuchi, Hisahiro Einaga

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

Decomposition of trifluoroacetic acid (TFA) was achieved with a tungstic heteropolyacid photocatalyst H3PW12O40· 6H2O in order to develop a technique for measures against TFA stationary sources. This is the first example of C-F bond cleavage in an environmentally harmful perfluoromethyl-group-containing compound using a homogeneous photocatalyst. The catalytic reaction proceeds in water at room temperature under UV-visible light irradiation in the presence of oxygen. The system produces only F- ions and CO2; the (mole of formed F-)/(mole of decomposed TFA) and (mole of formed CO2)/(mole of decomposed TFA) ratios were 2.91 and 2.09, respectively. GC/MS measurements showed no trace of other species such as environmentally undesirable CF4, which is the most stable perfluorocarbon and has a very high global warming potential. When the (initial TFA)/(initial catalyst) molar ratio was 20:1, the turnover number of TFA decomposition reached 5.58 by 72 h of irradiation, accompanying with no catalyst degradation. The catalytic reaction mechanism can be explained by a redox reaction between the catalyst and TFA, involving a photo-Kolbe process.

Original languageEnglish
Pages (from-to)418-422
Number of pages5
JournalEnvironmental Science and Technology
Volume37
Issue number2
DOIs
Publication statusPublished - Jan 15 2003
Externally publishedYes

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Trifluoroacetic Acid
Photocatalysts
Fluorides
fluoride
Ions
decomposition
Decomposition
ion
Water
acid
catalyst
water
Catalysts
irradiation
Irradiation
Fluorocarbons
Redox reactions
Global warming
cleavage
global warming

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry

Cite this

Decomposition of environmentally persistent trifluoroacetic acid to fluoride ions by a homogeneous photocatalyst in water. / Hori, Hisao; Takano, Yuko; Koike, Kazuhide; Takeuchi, Koji; Einaga, Hisahiro.

In: Environmental Science and Technology, Vol. 37, No. 2, 15.01.2003, p. 418-422.

Research output: Contribution to journalArticle

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