Deposition of photo-generated mixed-valent Fe(II)-Fe(III) complexes at the surface of Langmuir monolayers

Nobuo Kimizuka, Tsutomu Asai, Shinji Ohno, Kunitaka Fujiyoshi, Toyoki Kunitake

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A mixed-valent Fe(II)-Fe(III) complex was deposited at the surface of cationic monolayers by photoirradiation of the aqueous subphase containing equimolar Fe3+ and Fe(CN)3-6 ions. The photo-deposition process was detected in situ by the measurement of reflectance spectra at the air-water interface at a constant surface pressure. The present technique provides a first example of the photo-induced mineralization process at the air-water interface.

Original languageEnglish
Pages (from-to)245-248
Number of pages4
JournalSurface Science
Volume386
Issue number1-3
DOIs
Publication statusPublished - Oct 1 1997

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monomolecular films
Monolayers
Water
air
Air
water
Ions
reflectance
ions

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Deposition of photo-generated mixed-valent Fe(II)-Fe(III) complexes at the surface of Langmuir monolayers. / Kimizuka, Nobuo; Asai, Tsutomu; Ohno, Shinji; Fujiyoshi, Kunitaka; Kunitake, Toyoki.

In: Surface Science, Vol. 386, No. 1-3, 01.10.1997, p. 245-248.

Research output: Contribution to journalArticle

Kimizuka, Nobuo ; Asai, Tsutomu ; Ohno, Shinji ; Fujiyoshi, Kunitaka ; Kunitake, Toyoki. / Deposition of photo-generated mixed-valent Fe(II)-Fe(III) complexes at the surface of Langmuir monolayers. In: Surface Science. 1997 ; Vol. 386, No. 1-3. pp. 245-248.
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AU - Kunitake, Toyoki

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