Deposition of photo-generated mixed-valent Fe(II)-Fe(III) complexes at the surface of Langmuir monolayers

Nobuo Kimizuka, Tsutomu Asai, Shinji Ohno, Kunitaka Fujiyoshi, Toyoki Kunitake

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

A mixed-valent Fe(II)-Fe(III) complex was deposited at the surface of cationic monolayers by photoirradiation of the aqueous subphase containing equimolar Fe3+ and Fe(CN)3-6 ions. The photo-deposition process was detected in situ by the measurement of reflectance spectra at the air-water interface at a constant surface pressure. The present technique provides a first example of the photo-induced mineralization process at the air-water interface.

Original languageEnglish
Pages (from-to)245-248
Number of pages4
JournalSurface Science
Volume386
Issue number1-3
DOIs
Publication statusPublished - Oct 1 1997

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

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