Depth Profiling Analysis of Adsorbed Species on a Single Microparticle with Photoacoustic Spectroscopy

Yu Ming Hsueh, Akira Harata, Takehiko Kitamori, Tsuguo Sawada

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

A novel nondestructive evaluation method for the adsorption layer thickness of a single microparticle using the frequency characteristics of the photoacoustic signal magnitude and phase is proposed. The adsorption thickness of metal 8-quinolinol chelates on an Amberlite XAD-2 microparticle of about 300 um in diameter was estimated by the proposed method. Measurements were performed with a single particle, and adsorption thicknesses of 100 - 101 µm could be examined. A good agreement between the photoacoustic and microscopic determinations was obtained when the thermal diffusion length was longer than the adsorption thickness. The application range with respect to the relation between the thermal diffusion length and the adsorption thickness is discussed qualitatively on the basis of the experimental results of the frequency characteristics of the signal magnitude.

Original languageEnglish
Pages (from-to)71-75
Number of pages5
Journalanalytical sciences
Volume6
Issue number1
DOIs
Publication statusPublished - Jan 1 1990
Externally publishedYes

Fingerprint

Photoacoustic spectroscopy
Depth profiling
Adsorption
Thermal diffusion
Photoacoustic effect
Oxyquinoline
Metals

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

Cite this

Depth Profiling Analysis of Adsorbed Species on a Single Microparticle with Photoacoustic Spectroscopy. / Hsueh, Yu Ming; Harata, Akira; Kitamori, Takehiko; Sawada, Tsuguo.

In: analytical sciences, Vol. 6, No. 1, 01.01.1990, p. 71-75.

Research output: Contribution to journalArticle

Hsueh, Yu Ming ; Harata, Akira ; Kitamori, Takehiko ; Sawada, Tsuguo. / Depth Profiling Analysis of Adsorbed Species on a Single Microparticle with Photoacoustic Spectroscopy. In: analytical sciences. 1990 ; Vol. 6, No. 1. pp. 71-75.
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