TY - JOUR
T1 - Design of flexible lewis acidic sites in porous coordination polymers by using the viologen moiety
AU - Higuchi, Masakazu
AU - Nakamura, Kohei
AU - Horike, Satoshi
AU - Hijikata, Yuh
AU - Yanai, Nobuhiro
AU - Fukushima, Tomohiro
AU - Kim, Jungeun
AU - Kato, Kenichi
AU - Takata, Masaki
AU - Watanabe, Daisuke
AU - Oshima, Shinji
AU - Kitagawa, Susumu
PY - 2012/8/13
Y1 - 2012/8/13
N2 - Charged up: A novel porous coordination polymer with a charged organic surface (COS) comprising a zwitterionic organic linker, viologen, has been synthesized. The COS shows strong Lewis acidity accompanied with flexibility, and the isosteric heat of H2 adsorption is 9.5 kJ mol-1, which is comparable to that of open metal sites (OMSs).
AB - Charged up: A novel porous coordination polymer with a charged organic surface (COS) comprising a zwitterionic organic linker, viologen, has been synthesized. The COS shows strong Lewis acidity accompanied with flexibility, and the isosteric heat of H2 adsorption is 9.5 kJ mol-1, which is comparable to that of open metal sites (OMSs).
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U2 - 10.1002/anie.201203834
DO - 10.1002/anie.201203834
M3 - Article
C2 - 22807139
AN - SCOPUS:84864877905
SN - 1433-7851
VL - 51
SP - 8369
EP - 8372
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 33
ER -