Di-μ-α-pyrrolidinonato-bis[cis-diammine-chloroplatinum(III)] sulfate dihydrate: A head-to-head isomer

Ken Sakai, Itsuki Sakai, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

In the title compound, [PtIII2Cl2(C 4H6NO)2(NH3)4](SO 4)2H2O, the intradimer PtIII-PtIII distance is 2.6235 (13) Å. The axial PtIII-Cl bond distances for the N4 and N2O2 coordinated sites are 2.410 (5) and 2.446 (5) Å, respectively. The two Pt coordination planes are inclined at 16.3 (6)° and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 0.4°.

Original languageEnglish
Pages (from-to)m255-m258
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number3
DOIs
Publication statusPublished - Mar 1 2004

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this