Di-μ-α-pyrrolidinonato-bis[cis-diammine-chloroplatinum(III)] sulfate dihydrate: A head-to-head isomer

Ken Sakai; Itsuki Sakai; Takashi Kajiwara; Tasuku Ito

doi:10.1107/S1600536804002065

Di-μ-α-pyrrolidinonato-bis[cis-diammine-chloroplatinum(III)] sulfate dihydrate: A head-to-head isomer

Ken Sakai, Itsuki Sakai, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

In the title compound, [Pt^III₂Cl₂(C ₄H₆NO)₂(NH₃)₄](SO ₄)2H₂O, the intradimer Pt^III-Pt^III distance is 2.6235 (13) Å. The axial Pt^III-Cl bond distances for the N₄ and N₂O₂ coordinated sites are 2.410 (5) and 2.446 (5) Å, respectively. The two Pt coordination planes are inclined at 16.3 (6)° and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 0.4°.

Original language	English
Pages (from-to)	m255-m258
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	3
DOIs	https://doi.org/10.1107/S1600536804002065
Publication status	Published - Mar 1 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536804002065

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title = "Di-μ-α-pyrrolidinonato-bis[cis-diammine-chloroplatinum(III)] sulfate dihydrate: A head-to-head isomer",

abstract = "In the title compound, [PtIII2Cl2(C 4H6NO)2(NH3)4](SO 4)2H2O, the intradimer PtIII-PtIII distance is 2.6235 (13) {\AA}. The axial PtIII-Cl bond distances for the N4 and N2O2 coordinated sites are 2.410 (5) and 2.446 (5) {\AA}, respectively. The two Pt coordination planes are inclined at 16.3 (6)° and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 0.4°.",

author = "Ken Sakai and Itsuki Sakai and Takashi Kajiwara and Tasuku Ito",

year = "2004",

month = mar,

day = "1",

doi = "10.1107/S1600536804002065",

language = "English",

volume = "60",

pages = "m255--m258",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "3",

}

TY - JOUR

T1 - Di-μ-α-pyrrolidinonato-bis[cis-diammine-chloroplatinum(III)] sulfate dihydrate

T2 - A head-to-head isomer

AU - Sakai, Ken

AU - Sakai, Itsuki

AU - Kajiwara, Takashi

AU - Ito, Tasuku

PY - 2004/3/1

Y1 - 2004/3/1

N2 - In the title compound, [PtIII2Cl2(C 4H6NO)2(NH3)4](SO 4)2H2O, the intradimer PtIII-PtIII distance is 2.6235 (13) Å. The axial PtIII-Cl bond distances for the N4 and N2O2 coordinated sites are 2.410 (5) and 2.446 (5) Å, respectively. The two Pt coordination planes are inclined at 16.3 (6)° and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 0.4°.

AB - In the title compound, [PtIII2Cl2(C 4H6NO)2(NH3)4](SO 4)2H2O, the intradimer PtIII-PtIII distance is 2.6235 (13) Å. The axial PtIII-Cl bond distances for the N4 and N2O2 coordinated sites are 2.410 (5) and 2.446 (5) Å, respectively. The two Pt coordination planes are inclined at 16.3 (6)° and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 0.4°.

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U2 - 10.1107/S1600536804002065

DO - 10.1107/S1600536804002065

M3 - Article

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SN - 1600-5368

VL - 60

SP - m255-m258

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

Di-μ-α-pyrrolidinonato-bis[cis-diammine-chloroplatinum(III)] sulfate dihydrate: A head-to-head isomer

Abstract

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