Di-μ-2-aminopyridinato-bis[(2,2′-bipyridine)-platinum(II)] dinitrate tetrahydrate as a head-to-tail isomer

Mina Mizota, Ken Sakai

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

In the title compound, [Pt2(C10H8N 2)2(C5H5N2) 2](NO3)2·-4H2O, two 2-aminopyridinate ligands bridge two Pt atoms in a head-to-tail fashion, the Pt - Pt distance being 2.8724 (6) Å. The dimers form a one-dimensional stack based on π-π stacking interactions between the bpy (2,2′-bipyridine) units, where the interplanar separations are estimated as 3.44 (2) and 3.45 (1) Å. No metal-metal interaction exists between the dimers.

Original languageEnglish
Pages (from-to)m473-m476
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number4
DOIs
Publication statusPublished - Apr 1 2004
Externally publishedYes

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dinitrates
Platinum
Isomers
Dimers
platinum
isomers
Metals
dimers
metals
Ligands
interactions
Atoms
ligands
atoms

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "Di-μ-2-aminopyridinato-bis[(2,2′-bipyridine)-platinum(II)] dinitrate tetrahydrate as a head-to-tail isomer",
abstract = "In the title compound, [Pt2(C10H8N 2)2(C5H5N2) 2](NO3)2·-4H2O, two 2-aminopyridinate ligands bridge two Pt atoms in a head-to-tail fashion, the Pt - Pt distance being 2.8724 (6) {\AA}. The dimers form a one-dimensional stack based on π-π stacking interactions between the bpy (2,2′-bipyridine) units, where the interplanar separations are estimated as 3.44 (2) and 3.45 (1) {\AA}. No metal-metal interaction exists between the dimers.",
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T1 - Di-μ-2-aminopyridinato-bis[(2,2′-bipyridine)-platinum(II)] dinitrate tetrahydrate as a head-to-tail isomer

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AU - Sakai, Ken

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N2 - In the title compound, [Pt2(C10H8N 2)2(C5H5N2) 2](NO3)2·-4H2O, two 2-aminopyridinate ligands bridge two Pt atoms in a head-to-tail fashion, the Pt - Pt distance being 2.8724 (6) Å. The dimers form a one-dimensional stack based on π-π stacking interactions between the bpy (2,2′-bipyridine) units, where the interplanar separations are estimated as 3.44 (2) and 3.45 (1) Å. No metal-metal interaction exists between the dimers.

AB - In the title compound, [Pt2(C10H8N 2)2(C5H5N2) 2](NO3)2·-4H2O, two 2-aminopyridinate ligands bridge two Pt atoms in a head-to-tail fashion, the Pt - Pt distance being 2.8724 (6) Å. The dimers form a one-dimensional stack based on π-π stacking interactions between the bpy (2,2′-bipyridine) units, where the interplanar separations are estimated as 3.44 (2) and 3.45 (1) Å. No metal-metal interaction exists between the dimers.

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