Di-μ-a-pyrrolidinonato-bis[cis-diammine-platinum(II)] sulfate monohydrate as a head-to-head isomer

Ken Sakai, Itsuki Sakai, Neil D. Draper, Daniel B. Leznoff

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title compound, [Pt2II(C4H 6NO)2(NH3)4](SO4) ·H2O, the intradimer PtII-PtII distance is 2.9749 (11) Å, which is clearly shorter than the value of 3.029 (2) Å reported for a different salt of the same cation, viz. [Pt 2II(C4H6NO)2(NH 3)4]2(PF6)3-(NO 3)-H2O [Matsumoto et al. (1989). Inorg. Chem. 28, 2959- 2964]. The two Pt coordination planes are inclined to each other by 29.9 (5)°, and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 4.3 (8)°.

Original languageEnglish
Pages (from-to)m273-m276
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number3
DOIs
Publication statusPublished - Mar 1 2004
Externally publishedYes

Fingerprint

Platinum
Isomers
Cisplatin
Sulfates
Cations
sulfates
platinum
isomers
Salts
Positive ions
Ligands
salts
cations
ligands

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Di-μ-a-pyrrolidinonato-bis[cis-diammine-platinum(II)] sulfate monohydrate as a head-to-head isomer. / Sakai, Ken; Sakai, Itsuki; Draper, Neil D.; Leznoff, Daniel B.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 3, 01.03.2004, p. m273-m276.

Research output: Contribution to journalArticle

@article{58b5191c7154421887b16f5742b5c793,
title = "Di-μ-a-pyrrolidinonato-bis[cis-diammine-platinum(II)] sulfate monohydrate as a head-to-head isomer",
abstract = "In the title compound, [Pt2II(C4H 6NO)2(NH3)4](SO4) ·H2O, the intradimer PtII-PtII distance is 2.9749 (11) {\AA}, which is clearly shorter than the value of 3.029 (2) {\AA} reported for a different salt of the same cation, viz. [Pt 2II(C4H6NO)2(NH 3)4]2(PF6)3-(NO 3)-H2O [Matsumoto et al. (1989). Inorg. Chem. 28, 2959- 2964]. The two Pt coordination planes are inclined to each other by 29.9 (5)°, and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 4.3 (8)°.",
author = "Ken Sakai and Itsuki Sakai and Draper, {Neil D.} and Leznoff, {Daniel B.}",
year = "2004",
month = "3",
day = "1",
doi = "10.1107/S1600536804002442",
language = "English",
volume = "60",
pages = "m273--m276",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "3",

}

TY - JOUR

T1 - Di-μ-a-pyrrolidinonato-bis[cis-diammine-platinum(II)] sulfate monohydrate as a head-to-head isomer

AU - Sakai, Ken

AU - Sakai, Itsuki

AU - Draper, Neil D.

AU - Leznoff, Daniel B.

PY - 2004/3/1

Y1 - 2004/3/1

N2 - In the title compound, [Pt2II(C4H 6NO)2(NH3)4](SO4) ·H2O, the intradimer PtII-PtII distance is 2.9749 (11) Å, which is clearly shorter than the value of 3.029 (2) Å reported for a different salt of the same cation, viz. [Pt 2II(C4H6NO)2(NH 3)4]2(PF6)3-(NO 3)-H2O [Matsumoto et al. (1989). Inorg. Chem. 28, 2959- 2964]. The two Pt coordination planes are inclined to each other by 29.9 (5)°, and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 4.3 (8)°.

AB - In the title compound, [Pt2II(C4H 6NO)2(NH3)4](SO4) ·H2O, the intradimer PtII-PtII distance is 2.9749 (11) Å, which is clearly shorter than the value of 3.029 (2) Å reported for a different salt of the same cation, viz. [Pt 2II(C4H6NO)2(NH 3)4]2(PF6)3-(NO 3)-H2O [Matsumoto et al. (1989). Inorg. Chem. 28, 2959- 2964]. The two Pt coordination planes are inclined to each other by 29.9 (5)°, and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 4.3 (8)°.

UR - http://www.scopus.com/inward/record.url?scp=18444393403&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=18444393403&partnerID=8YFLogxK

U2 - 10.1107/S1600536804002442

DO - 10.1107/S1600536804002442

M3 - Article

AN - SCOPUS:18444393403

VL - 60

SP - m273-m276

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 3

ER -