Di-μ-pivalato-bis[cis-diammineplatinum(II)] bis(perchlorate) pivalic acid solvate

Ken Sakai; Eri Ishigami; Kazuo Yokokawa; Takashi Kajiwara; Tasuku Ito

doi:10.1107/S1600536803026503

Di-μ-pivalato-bis[cis-diammineplatinum(II)] bis(perchlorate) pivalic acid solvate

Ken Sakai, Eri Ishigami, Kazuo Yokokawa, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The intradimer Pt-Pt distance [3.0928 (9) Å] in the title compound, [Pt₂(μ-C₅H₉O₂) ₂(NH₃)₄]ClO₄)₂· C₅H₁₀O₂, is much longer than that reported for [Pt₂(μ-C₅H₉O₂) ₂(NH₃)₄](SO₄)·p-H ₂O [2.9011 (9) Å; Sakai, Ishigami, Yokokawa, Kajiwara & Ito (2003). Acta Cryst. E59, m443-m445]. The complex cation has a crystallographic mirror plane perpendicular to the Pt-Pt bond. The crystal packing is stabilized by both the hydrophilic and hydrophobic layers, which stack alternately along the c axis.

Original language	English
Pages (from-to)	m1178-m1180
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	12
DOIs	https://doi.org/10.1107/S1600536803026503
Publication status	Published - Dec 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536803026503

Cite this

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title = "Di-μ-pivalato-bis[cis-diammineplatinum(II)] bis(perchlorate) pivalic acid solvate",

abstract = "The intradimer Pt-Pt distance [3.0928 (9) {\AA}] in the title compound, [Pt2(μ-C5H9O2) 2(NH3)4]ClO4)2· C5H10O2, is much longer than that reported for [Pt2(μ-C5H9O2) 2(NH3)4](SO4)·p-H 2O [2.9011 (9) {\AA}; Sakai, Ishigami, Yokokawa, Kajiwara & Ito (2003). Acta Cryst. E59, m443-m445]. The complex cation has a crystallographic mirror plane perpendicular to the Pt-Pt bond. The crystal packing is stabilized by both the hydrophilic and hydrophobic layers, which stack alternately along the c axis.",

author = "Ken Sakai and Eri Ishigami and Kazuo Yokokawa and Takashi Kajiwara and Tasuku Ito",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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T1 - Di-μ-pivalato-bis[cis-diammineplatinum(II)] bis(perchlorate) pivalic acid solvate

AU - Sakai, Ken

AU - Ishigami, Eri

AU - Yokokawa, Kazuo

AU - Kajiwara, Takashi

AU - Ito, Tasuku

PY - 2003/12

Y1 - 2003/12

N2 - The intradimer Pt-Pt distance [3.0928 (9) Å] in the title compound, [Pt2(μ-C5H9O2) 2(NH3)4]ClO4)2· C5H10O2, is much longer than that reported for [Pt2(μ-C5H9O2) 2(NH3)4](SO4)·p-H 2O [2.9011 (9) Å; Sakai, Ishigami, Yokokawa, Kajiwara & Ito (2003). Acta Cryst. E59, m443-m445]. The complex cation has a crystallographic mirror plane perpendicular to the Pt-Pt bond. The crystal packing is stabilized by both the hydrophilic and hydrophobic layers, which stack alternately along the c axis.

AB - The intradimer Pt-Pt distance [3.0928 (9) Å] in the title compound, [Pt2(μ-C5H9O2) 2(NH3)4]ClO4)2· C5H10O2, is much longer than that reported for [Pt2(μ-C5H9O2) 2(NH3)4](SO4)·p-H 2O [2.9011 (9) Å; Sakai, Ishigami, Yokokawa, Kajiwara & Ito (2003). Acta Cryst. E59, m443-m445]. The complex cation has a crystallographic mirror plane perpendicular to the Pt-Pt bond. The crystal packing is stabilized by both the hydrophilic and hydrophobic layers, which stack alternately along the c axis.

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Di-μ-pivalato-bis[cis-diammineplatinum(II)] bis(perchlorate) pivalic acid solvate

Abstract

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