Di-μ-pivalato-bis[cis-diammineplatinum(II)] bis(perchlorate) pivalic acid solvate

Ken Sakai, Eri Ishigami, Kazuo Yokokawa, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The intradimer Pt-Pt distance [3.0928 (9) Å] in the title compound, [Pt2(μ-C5H9O2) 2(NH3)4]ClO4)2· C5H10O2, is much longer than that reported for [Pt2(μ-C5H9O2) 2(NH3)4](SO4)·p-H 2O [2.9011 (9) Å; Sakai, Ishigami, Yokokawa, Kajiwara & Ito (2003). Acta Cryst. E59, m443-m445]. The complex cation has a crystallographic mirror plane perpendicular to the Pt-Pt bond. The crystal packing is stabilized by both the hydrophilic and hydrophobic layers, which stack alternately along the c axis.

Original languageEnglish
Pages (from-to)m1178-m1180
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number12
DOIs
Publication statusPublished - Dec 1 2003
Externally publishedYes

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perchlorates
Cations
Mirrors
Positive ions
mirrors
cations
Crystals
acids
Acids
crystals
perchlorate
pivalic acid

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Di-μ-pivalato-bis[cis-diammineplatinum(II)] bis(perchlorate) pivalic acid solvate. / Sakai, Ken; Ishigami, Eri; Yokokawa, Kazuo; Kajiwara, Takashi; Ito, Tasuku.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, No. 12, 01.12.2003, p. m1178-m1180.

Research output: Contribution to journalArticle

Sakai, Ken ; Ishigami, Eri ; Yokokawa, Kazuo ; Kajiwara, Takashi ; Ito, Tasuku. / Di-μ-pivalato-bis[cis-diammineplatinum(II)] bis(perchlorate) pivalic acid solvate. In: Acta Crystallographica Section E: Structure Reports Online. 2003 ; Vol. 59, No. 12. pp. m1178-m1180.
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