Di-μ-pivalato-bis[cis-diammineplatinum(II)] bis(perchlorate) pivalic acid solvate

Ken Sakai, Eri Ishigami, Kazuo Yokokawa, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

The intradimer Pt-Pt distance [3.0928 (9) Å] in the title compound, [Pt2(μ-C5H9O2) 2(NH3)4]ClO4)2· C5H10O2, is much longer than that reported for [Pt2(μ-C5H9O2) 2(NH3)4](SO4)·p-H 2O [2.9011 (9) Å; Sakai, Ishigami, Yokokawa, Kajiwara & Ito (2003). Acta Cryst. E59, m443-m445]. The complex cation has a crystallographic mirror plane perpendicular to the Pt-Pt bond. The crystal packing is stabilized by both the hydrophilic and hydrophobic layers, which stack alternately along the c axis.

Original languageEnglish
Pages (from-to)m1178-m1180
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number12
DOIs
Publication statusPublished - Dec 1 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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