Di-μ-pivalato-bis[cis-diammineplatinum(II)] sulfate monohydrate

Ken Sakai, Eri Ishigami, Kazuo Yokokawa, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The title compound, [Pt2(NH3)4(C 5H9O2)2](SO4) ·H2O, does not form an infinite chain, but has discrete dimeric cations in the crystal structure. The intradimer Pt-Pt distance in the pivalate dimer [2.9011 (9) Å] is effectively shorter than that reported for the acetate analog [2.9713 (8) Å], demonstrating the strong electron-donating property of the bridging pivalate ligand.

Original languageEnglish
Pages (from-to)m443-m445
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number7
DOIs
Publication statusPublished - Jul 1 2003
Externally publishedYes

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Dimers
Sulfates
Cations
acetates
sulfates
Acetates
Crystal structure
Positive ions
Ligands
dimers
analogs
cations
ligands
crystal structure
Electrons
electrons

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Di-μ-pivalato-bis[cis-diammineplatinum(II)] sulfate monohydrate. / Sakai, Ken; Ishigami, Eri; Yokokawa, Kazuo; Kajiwara, Takashi; Ito, Tasuku.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, No. 7, 01.07.2003, p. m443-m445.

Research output: Contribution to journalArticle

Sakai, Ken ; Ishigami, Eri ; Yokokawa, Kazuo ; Kajiwara, Takashi ; Ito, Tasuku. / Di-μ-pivalato-bis[cis-diammineplatinum(II)] sulfate monohydrate. In: Acta Crystallographica Section E: Structure Reports Online. 2003 ; Vol. 59, No. 7. pp. m443-m445.
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