Di-μ-pivalato-bis[cis-diammineplatinum(II)] sulfate monohydrate

Ken Sakai, Eri Ishigami, Kazuo Yokokawa, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The title compound, [Pt2(NH3)4(C 5H9O2)2](SO4) ·H2O, does not form an infinite chain, but has discrete dimeric cations in the crystal structure. The intradimer Pt-Pt distance in the pivalate dimer [2.9011 (9) Å] is effectively shorter than that reported for the acetate analog [2.9713 (8) Å], demonstrating the strong electron-donating property of the bridging pivalate ligand.

Original languageEnglish
Pages (from-to)m443-m445
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number7
DOIs
Publication statusPublished - Jul 1 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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