In the title complex, [FeIIFeIII 2(C9H10BN6)2(CN) 6(CH3OH)4]-2CH3OH, two [FeIII(Tp)(CN)3]- anions [Tp is hydrotris(pyrazoylborate)] are bridged by an [FeII(MeOH)4] 2+ cation, forming a centrosymmetric trinuclear unit. These units are connected via O - HO and O - HN hydrogen bonds involving the uncoordinated methanol solvent molecules, forming a three-dimensional network.
|Journal||Acta Crystallographica Section E: Structure Reports Online|
|Publication status||Published - Feb 2014|
All Science Journal Classification (ASJC) codes
- Materials Science(all)
- Condensed Matter Physics