Di-μ-tricyanido-tetracyanidobis[hydrotris(pyrazoylborato)] tetramethanoldiiron(III)iron(II) dimethanol disolvate

Kuirun Zhang, Osamu Sato

Research output: Contribution to journalArticle

Abstract

In the title complex, [FeIIFeIII 2(C9H10BN6)2(CN) 6(CH3OH)4]-2CH3OH, two [FeIII(Tp)(CN)3]- anions [Tp is hydrotris(pyrazoylborate)] are bridged by an [FeII(MeOH)4] 2+ cation, forming a centrosymmetric trinuclear unit. These units are connected via O - HO and O - HN hydrogen bonds involving the uncoordinated methanol solvent molecules, forming a three-dimensional network.

Original languageEnglish
Pages (from-to)m56
JournalActa Crystallographica Section E: Structure Reports Online
Volume70
Issue number2
DOIs
Publication statusPublished - Feb 1 2014

Fingerprint

Anions
Methanol
Cations
Hydrogen bonds
Negative ions
Iron
methyl alcohol
Positive ions
hydrogen bonds
anions
iron
cations
Molecules
molecules

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

@article{c169f121c551438fa1424395ee8f9201,
title = "Di-μ-tricyanido-tetracyanidobis[hydrotris(pyrazoylborato)] tetramethanoldiiron(III)iron(II) dimethanol disolvate",
abstract = "In the title complex, [FeIIFeIII 2(C9H10BN6)2(CN) 6(CH3OH)4]-2CH3OH, two [FeIII(Tp)(CN)3]- anions [Tp is hydrotris(pyrazoylborate)] are bridged by an [FeII(MeOH)4] 2+ cation, forming a centrosymmetric trinuclear unit. These units are connected via O - HO and O - HN hydrogen bonds involving the uncoordinated methanol solvent molecules, forming a three-dimensional network.",
author = "Kuirun Zhang and Osamu Sato",
year = "2014",
month = "2",
day = "1",
doi = "10.1107/S1600536814001019",
language = "English",
volume = "70",
pages = "m56",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "2",

}

TY - JOUR

T1 - Di-μ-tricyanido-tetracyanidobis[hydrotris(pyrazoylborato)] tetramethanoldiiron(III)iron(II) dimethanol disolvate

AU - Zhang, Kuirun

AU - Sato, Osamu

PY - 2014/2/1

Y1 - 2014/2/1

N2 - In the title complex, [FeIIFeIII 2(C9H10BN6)2(CN) 6(CH3OH)4]-2CH3OH, two [FeIII(Tp)(CN)3]- anions [Tp is hydrotris(pyrazoylborate)] are bridged by an [FeII(MeOH)4] 2+ cation, forming a centrosymmetric trinuclear unit. These units are connected via O - HO and O - HN hydrogen bonds involving the uncoordinated methanol solvent molecules, forming a three-dimensional network.

AB - In the title complex, [FeIIFeIII 2(C9H10BN6)2(CN) 6(CH3OH)4]-2CH3OH, two [FeIII(Tp)(CN)3]- anions [Tp is hydrotris(pyrazoylborate)] are bridged by an [FeII(MeOH)4] 2+ cation, forming a centrosymmetric trinuclear unit. These units are connected via O - HO and O - HN hydrogen bonds involving the uncoordinated methanol solvent molecules, forming a three-dimensional network.

UR - http://www.scopus.com/inward/record.url?scp=84893696587&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84893696587&partnerID=8YFLogxK

U2 - 10.1107/S1600536814001019

DO - 10.1107/S1600536814001019

M3 - Article

AN - SCOPUS:84893696587

VL - 70

SP - m56

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 2

ER -