TY - JOUR
T1 - Di-μ-tricyanido-tetracyanidobis[hydrotris(pyrazoylborato)] tetramethanoldiiron(III)iron(II) dimethanol disolvate
AU - Zhang, Kuirun
AU - Sato, Osamu
PY - 2014/2
Y1 - 2014/2
N2 - In the title complex, [FeIIFeIII 2(C9H10BN6)2(CN) 6(CH3OH)4]-2CH3OH, two [FeIII(Tp)(CN)3]- anions [Tp is hydrotris(pyrazoylborate)] are bridged by an [FeII(MeOH)4] 2+ cation, forming a centrosymmetric trinuclear unit. These units are connected via O - HO and O - HN hydrogen bonds involving the uncoordinated methanol solvent molecules, forming a three-dimensional network.
AB - In the title complex, [FeIIFeIII 2(C9H10BN6)2(CN) 6(CH3OH)4]-2CH3OH, two [FeIII(Tp)(CN)3]- anions [Tp is hydrotris(pyrazoylborate)] are bridged by an [FeII(MeOH)4] 2+ cation, forming a centrosymmetric trinuclear unit. These units are connected via O - HO and O - HN hydrogen bonds involving the uncoordinated methanol solvent molecules, forming a three-dimensional network.
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U2 - 10.1107/S1600536814001019
DO - 10.1107/S1600536814001019
M3 - Article
AN - SCOPUS:84893696587
SN - 1600-5368
VL - 70
SP - m56
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 2
ER -