Di-μ2-acetato-1:2κ2 O:O′;2: 3κ2 O:O′-bis{μ2-4,4′-dichloro-2, 2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato} -1:2κ6 O,N,N′,O′:O,O′;2:3κ6 O,O′:O,N,N′,O′-tricadmium

Koji Kubono, Keita Tani, Kunihiko Yokoi, Teruo Shinmyozu, Kenta Goto

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In the title linear homo-trinuclear complex, [Cd3(C 19H18Cl2N2O2)2(C 2H3O2)2], the central CdII atom is located on a centre of inversion and has a distorted octahedral coordination geometry formed by four O atoms from two bidentate/tetradentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal CdII atom is square-pyramidal with the tetradentate part of the ligand in the basal plane and one O atom from an acetate ligand occupying the apical site. The six-membered CdN2C 3 ring adopts a chair conformation. The acetate-bridged Cd⋯Cd distance is 3.3071 (2) Å. The crystal structure is stabilized by C-H⋯O hydrogen bonds, which form C(7) chain motifs and give rise to a two-dimensional supramolecular network structure lying parallel to the ab plane.

Original languageEnglish
Pages (from-to)m629-m630
JournalActa Crystallographica Section E: Structure Reports Online
Volume69
Issue number12
DOIs
Publication statusPublished - Dec 1 2013

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

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