Di-μ2-acetato-1:2κ2 O:O′;2: 3κ2 O:O′-bis{μ2-4,4′-dichloro-2, 2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato} -1:2κ6 O,N,N′,O′:O,O′;2:3κ6 O,O′:O,N,N′,O′-tricadmium

Koji Kubono, Keita Tani, Kunihiko Yokoi, Teruo Shinmyozu, Kenta Goto

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Abstract

In the title linear homo-trinuclear complex, [Cd3(C 19H18Cl2N2O2)2(C 2H3O2)2], the central CdII atom is located on a centre of inversion and has a distorted octahedral coordination geometry formed by four O atoms from two bidentate/tetradentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal CdII atom is square-pyramidal with the tetradentate part of the ligand in the basal plane and one O atom from an acetate ligand occupying the apical site. The six-membered CdN2C 3 ring adopts a chair conformation. The acetate-bridged Cd⋯Cd distance is 3.3071 (2) Å. The crystal structure is stabilized by C-H⋯O hydrogen bonds, which form C(7) chain motifs and give rise to a two-dimensional supramolecular network structure lying parallel to the ab plane.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume69
Issue number12
DOIs
Publication statusPublished - Dec 1 2013

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Atoms
Ligands
acetates
ligands
Acetates
atoms
Schiff Bases
Geometry
geometry
imines
seats
Conformations
Hydrogen bonds
Crystal structure
inversions
hydrogen bonds
crystal structure
rings

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

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title = "Di-μ2-acetato-1:2κ2 O:O′;2: 3κ2 O:O′-bis{μ2-4,4′-dichloro-2, 2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato} -1:2κ6 O,N,N′,O′:O,O′;2:3κ6 O,O′:O,N,N′,O′-tricadmium",
abstract = "In the title linear homo-trinuclear complex, [Cd3(C 19H18Cl2N2O2)2(C 2H3O2)2], the central CdII atom is located on a centre of inversion and has a distorted octahedral coordination geometry formed by four O atoms from two bidentate/tetradentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal CdII atom is square-pyramidal with the tetradentate part of the ligand in the basal plane and one O atom from an acetate ligand occupying the apical site. The six-membered CdN2C 3 ring adopts a chair conformation. The acetate-bridged Cd⋯Cd distance is 3.3071 (2) {\AA}. The crystal structure is stabilized by C-H⋯O hydrogen bonds, which form C(7) chain motifs and give rise to a two-dimensional supramolecular network structure lying parallel to the ab plane.",
author = "Koji Kubono and Keita Tani and Kunihiko Yokoi and Teruo Shinmyozu and Kenta Goto",
year = "2013",
month = "12",
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language = "English",
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journal = "Acta Crystallographica Section E: Structure Reports Online",
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TY - JOUR

T1 - Di-μ2-acetato-1:2κ2 O:O′;2

T2 - 3κ2 O:O′-bis{μ2-4,4′-dichloro-2, 2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato} -1:2κ6 O,N,N′,O′:O,O′;2:3κ6 O,O′:O,N,N′,O′-tricadmium

AU - Kubono, Koji

AU - Tani, Keita

AU - Yokoi, Kunihiko

AU - Shinmyozu, Teruo

AU - Goto, Kenta

PY - 2013/12/1

Y1 - 2013/12/1

N2 - In the title linear homo-trinuclear complex, [Cd3(C 19H18Cl2N2O2)2(C 2H3O2)2], the central CdII atom is located on a centre of inversion and has a distorted octahedral coordination geometry formed by four O atoms from two bidentate/tetradentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal CdII atom is square-pyramidal with the tetradentate part of the ligand in the basal plane and one O atom from an acetate ligand occupying the apical site. The six-membered CdN2C 3 ring adopts a chair conformation. The acetate-bridged Cd⋯Cd distance is 3.3071 (2) Å. The crystal structure is stabilized by C-H⋯O hydrogen bonds, which form C(7) chain motifs and give rise to a two-dimensional supramolecular network structure lying parallel to the ab plane.

AB - In the title linear homo-trinuclear complex, [Cd3(C 19H18Cl2N2O2)2(C 2H3O2)2], the central CdII atom is located on a centre of inversion and has a distorted octahedral coordination geometry formed by four O atoms from two bidentate/tetradentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal CdII atom is square-pyramidal with the tetradentate part of the ligand in the basal plane and one O atom from an acetate ligand occupying the apical site. The six-membered CdN2C 3 ring adopts a chair conformation. The acetate-bridged Cd⋯Cd distance is 3.3071 (2) Å. The crystal structure is stabilized by C-H⋯O hydrogen bonds, which form C(7) chain motifs and give rise to a two-dimensional supramolecular network structure lying parallel to the ab plane.

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