Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate

Toshiki Yamaguchi; Shigeyuki Masaoka; Ken Sakai

doi:10.1107/S1600536808036805

Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate

Toshiki Yamaguchi, Shigeyuki Masaoka, Ken Sakai

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The title compound, [Fe(C10H20O5)(H2O)2][Fe2(C4N2S2)4]·2C10H20O5, consists of an [Fe^II(15-crown-5)(H2O)2]²⁺ cation, sandwiched between and O - H⋯O hydrogen bonded by two additional 15-crown-5 ether mol-ecules and two independent [Fe^III(mnt)2] ^- anions, where 15-crown-5 ether denotes 1,4,7,10,13-penta-oxacyclo- penta-decane and mnt denotes cis-1,2-dicyano-1,2-ethyl-enedithiol-ate. Each independent [Fe^III(mnt)2]^- unit forms a centrosymmetric dimer supported by two inter-monomer Fe^III - S bonds [Fe - S = 2.4715 (9) and 2.4452 (9) Å]. In the crystal structure, the dimers form one-dimensional π-π stacks along the a axis, with an inter-planar separation of 3.38 (6) Å.

Original language	English
Pages (from-to)	m1557-m1558
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	12
DOIs	https://doi.org/10.1107/S1600536808036805
Publication status	Published - 2008

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Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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Yamaguchi, T., Masaoka, S., & Sakai, K. (2008). Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate. Acta Crystallographica Section E: Structure Reports Online, 64(12), m1557-m1558. https://doi.org/10.1107/S1600536808036805

Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate. / Yamaguchi, Toshiki; Masaoka, Shigeyuki; Sakai, Ken.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 64, No. 12, 2008, p. m1557-m1558.

Research output: Contribution to journal › Article › peer-review

Yamaguchi, T, Masaoka, S & Sakai, K 2008, 'Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate', Acta Crystallographica Section E: Structure Reports Online, vol. 64, no. 12, pp. m1557-m1558. https://doi.org/10.1107/S1600536808036805

Yamaguchi, Toshiki ; Masaoka, Shigeyuki ; Sakai, Ken. / Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate. In: Acta Crystallographica Section E: Structure Reports Online. 2008 ; Vol. 64, No. 12. pp. m1557-m1558.

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title = "Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate",

abstract = "The title compound, [Fe(C10H20O5)(H2O)2][Fe2(C4N2S2)4]·2C10H20O5, consists of an [FeII(15-crown-5)(H2O)2]2+ cation, sandwiched between and O - H⋯O hydrogen bonded by two additional 15-crown-5 ether mol-ecules and two independent [FeIII(mnt)2] - anions, where 15-crown-5 ether denotes 1,4,7,10,13-penta-oxacyclo- penta-decane and mnt denotes cis-1,2-dicyano-1,2-ethyl-enedithiol-ate. Each independent [FeIII(mnt)2]- unit forms a centrosymmetric dimer supported by two inter-monomer FeIII - S bonds [Fe - S = 2.4715 (9) and 2.4452 (9) {\AA}]. In the crystal structure, the dimers form one-dimensional π-π stacks along the a axis, with an inter-planar separation of 3.38 (6) {\AA}.",

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T1 - Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate

AU - Yamaguchi, Toshiki

AU - Masaoka, Shigeyuki

AU - Sakai, Ken

PY - 2008

Y1 - 2008

N2 - The title compound, [Fe(C10H20O5)(H2O)2][Fe2(C4N2S2)4]·2C10H20O5, consists of an [FeII(15-crown-5)(H2O)2]2+ cation, sandwiched between and O - H⋯O hydrogen bonded by two additional 15-crown-5 ether mol-ecules and two independent [FeIII(mnt)2] - anions, where 15-crown-5 ether denotes 1,4,7,10,13-penta-oxacyclo- penta-decane and mnt denotes cis-1,2-dicyano-1,2-ethyl-enedithiol-ate. Each independent [FeIII(mnt)2]- unit forms a centrosymmetric dimer supported by two inter-monomer FeIII - S bonds [Fe - S = 2.4715 (9) and 2.4452 (9) Å]. In the crystal structure, the dimers form one-dimensional π-π stacks along the a axis, with an inter-planar separation of 3.38 (6) Å.

AB - The title compound, [Fe(C10H20O5)(H2O)2][Fe2(C4N2S2)4]·2C10H20O5, consists of an [FeII(15-crown-5)(H2O)2]2+ cation, sandwiched between and O - H⋯O hydrogen bonded by two additional 15-crown-5 ether mol-ecules and two independent [FeIII(mnt)2] - anions, where 15-crown-5 ether denotes 1,4,7,10,13-penta-oxacyclo- penta-decane and mnt denotes cis-1,2-dicyano-1,2-ethyl-enedithiol-ate. Each independent [FeIII(mnt)2]- unit forms a centrosymmetric dimer supported by two inter-monomer FeIII - S bonds [Fe - S = 2.4715 (9) and 2.4452 (9) Å]. In the crystal structure, the dimers form one-dimensional π-π stacks along the a axis, with an inter-planar separation of 3.38 (6) Å.

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Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate

Abstract

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