Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate

Toshiki Yamaguchi, Shigeyuki Masaoka, Ken Sakai

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6 Citations (Scopus)

Abstract

The title compound, [Fe(C10H20O5)(H2O)2][Fe2(C4N2S2)4]·2C10H20O5, consists of an [FeII(15-crown-5)(H2O)2]2+ cation, sandwiched between and O - H⋯O hydrogen bonded by two additional 15-crown-5 ether mol-ecules and two independent [FeIII(mnt)2] - anions, where 15-crown-5 ether denotes 1,4,7,10,13-penta-oxacyclo- penta-decane and mnt denotes cis-1,2-dicyano-1,2-ethyl-enedithiol-ate. Each independent [FeIII(mnt)2]- unit forms a centrosymmetric dimer supported by two inter-monomer FeIII - S bonds [Fe - S = 2.4715 (9) and 2.4452 (9) Å]. In the crystal structure, the dimers form one-dimensional π-π stacks along the a axis, with an inter-planar separation of 3.38 (6) Å.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number12
DOIs
Publication statusPublished - Dec 12 2008

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ferrates
Dimers
Ethers
ethers
Iron
dimers
iron
Ether
Negative ions
monomers
Monomers
Crystal structure
Positive ions
anions
cations
Hydrogen
crystal structure
Anions
Cations
hydrogen

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

@article{254e6ba0b75e4dbdb80938f3149b008c,
title = "Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate",
abstract = "The title compound, [Fe(C10H20O5)(H2O)2][Fe2(C4N2S2)4]·2C10H20O5, consists of an [FeII(15-crown-5)(H2O)2]2+ cation, sandwiched between and O - H⋯O hydrogen bonded by two additional 15-crown-5 ether mol-ecules and two independent [FeIII(mnt)2] - anions, where 15-crown-5 ether denotes 1,4,7,10,13-penta-oxacyclo- penta-decane and mnt denotes cis-1,2-dicyano-1,2-ethyl-enedithiol-ate. Each independent [FeIII(mnt)2]- unit forms a centrosymmetric dimer supported by two inter-monomer FeIII - S bonds [Fe - S = 2.4715 (9) and 2.4452 (9) {\AA}]. In the crystal structure, the dimers form one-dimensional π-π stacks along the a axis, with an inter-planar separation of 3.38 (6) {\AA}.",
author = "Toshiki Yamaguchi and Shigeyuki Masaoka and Ken Sakai",
year = "2008",
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doi = "10.1107/S1600536808036805",
language = "English",
volume = "64",
journal = "Acta Crystallographica Section E: Structure Reports Online",
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TY - JOUR

T1 - Diaqua-(1,4,7,10,13-penta-oxacyclo-penta-deca-ne)iron(II) bis-(μ-cis-1,2-dicyano-1,2-ethyl-enedithiol-ato)bis-[(cis-1,2-dicyano-1, 2-ethyl-enedithiol-ato)ferrate(III)] 1,4,7,10,13-penta-oxacyclo-penta-decane disolvate

AU - Yamaguchi, Toshiki

AU - Masaoka, Shigeyuki

AU - Sakai, Ken

PY - 2008/12/12

Y1 - 2008/12/12

N2 - The title compound, [Fe(C10H20O5)(H2O)2][Fe2(C4N2S2)4]·2C10H20O5, consists of an [FeII(15-crown-5)(H2O)2]2+ cation, sandwiched between and O - H⋯O hydrogen bonded by two additional 15-crown-5 ether mol-ecules and two independent [FeIII(mnt)2] - anions, where 15-crown-5 ether denotes 1,4,7,10,13-penta-oxacyclo- penta-decane and mnt denotes cis-1,2-dicyano-1,2-ethyl-enedithiol-ate. Each independent [FeIII(mnt)2]- unit forms a centrosymmetric dimer supported by two inter-monomer FeIII - S bonds [Fe - S = 2.4715 (9) and 2.4452 (9) Å]. In the crystal structure, the dimers form one-dimensional π-π stacks along the a axis, with an inter-planar separation of 3.38 (6) Å.

AB - The title compound, [Fe(C10H20O5)(H2O)2][Fe2(C4N2S2)4]·2C10H20O5, consists of an [FeII(15-crown-5)(H2O)2]2+ cation, sandwiched between and O - H⋯O hydrogen bonded by two additional 15-crown-5 ether mol-ecules and two independent [FeIII(mnt)2] - anions, where 15-crown-5 ether denotes 1,4,7,10,13-penta-oxacyclo- penta-decane and mnt denotes cis-1,2-dicyano-1,2-ethyl-enedithiol-ate. Each independent [FeIII(mnt)2]- unit forms a centrosymmetric dimer supported by two inter-monomer FeIII - S bonds [Fe - S = 2.4715 (9) and 2.4452 (9) Å]. In the crystal structure, the dimers form one-dimensional π-π stacks along the a axis, with an inter-planar separation of 3.38 (6) Å.

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