Diarylbibenzofuranone-based dynamic covalent polymer gels prepared via radical polymerization and subsequent polymer reaction

Keiichi Imato, Masamichi Nishihara, Atsushi Irie, Atsushi Takahara, Hideyuki Otsuka

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

Diarylbibenzofuranone (DABBF) is a dynamic covalent bonding unit, which is in equilibrium with the corresponding radicals at room temperature, and polymers with DABBF linkages show notable properties such as self-healing. The preparation routes have been strictly limited, however, and no polymer with the linkages has been synthesized via radical polymerization because of the strong antioxidant activity of DABBF. Here we present a new method to prepare DABBF-containing polymers via radical polymerization of the precursor, arylbenzofuranone (ABF), and subsequent polymer reaction, dimerization of ABF units in the linear polymers. Polymer gels cross-linked by DABBF linkages were obtained against the relatively strong antioxidant activity of ABF and showed dynamic network reorganization at room temperature.

Original languageEnglish
Pages (from-to)58-68
Number of pages11
JournalGels
Volume1
Issue number1
DOIs
Publication statusPublished - Sep 2015

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Biomaterials
  • Organic Chemistry
  • Polymers and Plastics

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