Diastereo-differentiating hydrogen transfer in 5-deazaflavins

Seiji Shinkai, Akito Kawase, Toshiro Yamaguchi, Osamu Manabe

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

Reduction of 5-deazaisoalloxazinophanes dFl(n) in which N(3) and O(2′ α) in the 10-(2-hydroxy)phenyl group were linked by a (CH 2)n chain (n = 6,8) resulted in the boat-shaped 1,5-dihydro forms dFlred(n); hydrogen transfer to dFl(n) and from dFlred(n) occurred exclusively at the axial C(5) position.

Original languageEnglish
Pages (from-to)457-458
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number7
DOIs
Publication statusPublished - Jan 1 1988
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

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