Diastereo-differentiating hydrogen transfer in 5-deazaflavins

Seiji Shinkai; Akito Kawase; Toshiro Yamaguchi; Osamu Manabe

doi:10.1039/C39880000457

Diastereo-differentiating hydrogen transfer in 5-deazaflavins

Seiji Shinkai, Akito Kawase, Toshiro Yamaguchi, Osamu Manabe

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Reduction of 5-deazaisoalloxazinophanes dFl(n) in which N(3) and O(2′ α) in the 10-(2-hydroxy)phenyl group were linked by a (CH ₂)_n chain (n = 6,8) resulted in the boat-shaped 1,5-dihydro forms dFl_red(n); hydrogen transfer to dFl(n) and from dFl_red(n) occurred exclusively at the axial C(5) position.

Original language	English
Pages (from-to)	457-458
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	7
DOIs	https://doi.org/10.1039/C39880000457
Publication status	Published - Jan 1 1988
Externally published	Yes

All Science Journal Classification (ASJC) codes

Molecular Medicine

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title = "Diastereo-differentiating hydrogen transfer in 5-deazaflavins",

abstract = "Reduction of 5-deazaisoalloxazinophanes dFl(n) in which N(3) and O(2′ α) in the 10-(2-hydroxy)phenyl group were linked by a (CH 2)n chain (n = 6,8) resulted in the boat-shaped 1,5-dihydro forms dFlred(n); hydrogen transfer to dFl(n) and from dFlred(n) occurred exclusively at the axial C(5) position.",

author = "Seiji Shinkai and Akito Kawase and Toshiro Yamaguchi and Osamu Manabe",

year = "1988",

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doi = "10.1039/C39880000457",

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journal = "Chemical Communications",

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T1 - Diastereo-differentiating hydrogen transfer in 5-deazaflavins

AU - Shinkai, Seiji

AU - Kawase, Akito

AU - Yamaguchi, Toshiro

AU - Manabe, Osamu

PY - 1988/1/1

Y1 - 1988/1/1

N2 - Reduction of 5-deazaisoalloxazinophanes dFl(n) in which N(3) and O(2′ α) in the 10-(2-hydroxy)phenyl group were linked by a (CH 2)n chain (n = 6,8) resulted in the boat-shaped 1,5-dihydro forms dFlred(n); hydrogen transfer to dFl(n) and from dFlred(n) occurred exclusively at the axial C(5) position.

AB - Reduction of 5-deazaisoalloxazinophanes dFl(n) in which N(3) and O(2′ α) in the 10-(2-hydroxy)phenyl group were linked by a (CH 2)n chain (n = 6,8) resulted in the boat-shaped 1,5-dihydro forms dFlred(n); hydrogen transfer to dFl(n) and from dFlred(n) occurred exclusively at the axial C(5) position.

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JO - Chemical Communications

JF - Chemical Communications

IS - 7

ER -

Diastereo-differentiating hydrogen transfer in 5-deazaflavins

Abstract

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