TY - JOUR
T1 - Dicopper and disilver complexes of octaphyrin(1.1.1.1.1.1.1.1)
T2 - Reversible hydrolytic cleavage of the pyrrolic ring to a keto-imine
AU - Shimizu, Soji
AU - Tanaka, Yasuo
AU - Youfu, Katsuyuki
AU - Osuka, Atsuhiro
N1 - Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2005/6/13
Y1 - 2005/6/13
N2 - (Chemical Equation Presented) Metallooctaphyrin complexes: Dimetalation of perfluorinated [36]octaphyrin with copper(II) results in the hydrolytic ring opening of one of the pyrrole rings (see structure), whereas with silver ions perfluorinated [36]octaphyrin and meso-pentafluorophenyl-substituted [36]octaphyrin gave disilver(I) complexes of [34]octaphyrin.
AB - (Chemical Equation Presented) Metallooctaphyrin complexes: Dimetalation of perfluorinated [36]octaphyrin with copper(II) results in the hydrolytic ring opening of one of the pyrrole rings (see structure), whereas with silver ions perfluorinated [36]octaphyrin and meso-pentafluorophenyl-substituted [36]octaphyrin gave disilver(I) complexes of [34]octaphyrin.
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U2 - 10.1002/anie.200500676
DO - 10.1002/anie.200500676
M3 - Article
C2 - 15887208
AN - SCOPUS:20444450615
SN - 1433-7851
VL - 44
SP - 3726
EP - 3729
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 24
ER -