Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand

Yoshimitsu Tachi, Kazuki Aita, Shinichi Teramae, Fumito Tani, Yoshinori Naruta, Shunichi Fukuzumi, Shinobu Itoh

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

A dicopper(I) complex supported by a novel asymmetric pentapyridine dinucleating ligand, consisting of tetradentate and tridentate metal-binding sites, has been synthesized and characterized. The dicopper(I) complex reacted with molecular oxygen at a low temperature to give an unprecedented μ-peroxo dicopper(II) complex presumably having μ-η12 binding mode, the spectroscopic features and the reactivity of which have been explored in detail.

Original languageEnglish
Pages (from-to)4558-4560
Number of pages3
JournalInorganic Chemistry
Volume43
Issue number15
DOIs
Publication statusPublished - Jul 26 2004

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Molecular oxygen
reactivity
Metals
Binding Sites
Oxygen
Ligands
ligands
oxygen
metals
Temperature

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Tachi, Y., Aita, K., Teramae, S., Tani, F., Naruta, Y., Fukuzumi, S., & Itoh, S. (2004). Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand. Inorganic Chemistry, 43(15), 4558-4560. https://doi.org/10.1021/ic049524g

Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand. / Tachi, Yoshimitsu; Aita, Kazuki; Teramae, Shinichi; Tani, Fumito; Naruta, Yoshinori; Fukuzumi, Shunichi; Itoh, Shinobu.

In: Inorganic Chemistry, Vol. 43, No. 15, 26.07.2004, p. 4558-4560.

Research output: Contribution to journalArticle

Tachi, Y, Aita, K, Teramae, S, Tani, F, Naruta, Y, Fukuzumi, S & Itoh, S 2004, 'Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand', Inorganic Chemistry, vol. 43, no. 15, pp. 4558-4560. https://doi.org/10.1021/ic049524g
Tachi, Yoshimitsu ; Aita, Kazuki ; Teramae, Shinichi ; Tani, Fumito ; Naruta, Yoshinori ; Fukuzumi, Shunichi ; Itoh, Shinobu. / Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand. In: Inorganic Chemistry. 2004 ; Vol. 43, No. 15. pp. 4558-4560.
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