Dielectric Property-Electrooptical Effect Relationships of Polymer/Liquid-Crystal Composite Films

Akira Miyamoto, Hirotsugu Kikuchi, Satoshi Kobayashi, Yasuhiro Morimura, Tisato Kajiyama

Research output: Contribution to journalArticlepeer-review

87 Citations (Scopus)

Abstract

The dielectric properties of a polymer/liquid-crystal (LC) composite film and their influence on the electrooptical response have been investigated. The composite film in which an LC material is embedded as a continuous phase in a three-dimensional spongy polymer matrix shows an electrooptical effect based on a novel concept of light scattering. The electrooptical response speed for the composite film is proportional to ~ ΔεE2, where Δε is the dielectric anisotropy of the LC, and E is the electric field. The dielectric properties of the composite film are approximately explained by the series-connected dielectric composite model consisting of the polymer matrix and the LC phases. Since the magnitude of the ratio of the dielectric constants of both polymer and LC phases, ε′p/ε′lc, is not always the same as that of the electric conductivities, σPlc, the magnitude of an ac electric field in the LC phase is modulated and depends on the frequency of the externally applied ac electric field. Further, the frequency dependence of the magnitude of an ac electric field in the LC domain is calculated on the basis of the series-connected dielectric composite model. The calculated result explains qualitatively the frequency dependence of the electrooptical response rise time for the composite film. Also, it is concluded, from the dielectric model calculation, that the electrooptical response rise speed in a wide frequency range of electric field could be improved by using a polymer matrix with greater magnitudes of both electric conductivity and dielectric constant.

Original languageEnglish
Pages (from-to)3915-3920
Number of pages6
JournalMacromolecules
Volume24
Issue number13
DOIs
Publication statusPublished - Jun 1 1991

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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