Diethynylbenzene-based liquid crystalline semiconductor for solution-processable organic thin-film transistors

Pramod Kandoth Madathil, Benoît Heinrich, Bertrand Donnio, Fabrice Dominique Mathevet, Jean Louis Fave, Daniel Guillon, Andre Jean Attias, Changjin Lee, Tae Dong Kim, Kwang Sup Lee

    Research output: Contribution to journalArticlepeer-review

    3 Citations (Scopus)


    We report here the synthesis and characterization of novel diethynylbenzene-based liquid crystalline semiconductor (P1) for organic thin-film transistors (OTFTs), Compound P1 was synthesized by the Sonogashira coupling reaction between 2-bromo-5-(4-hexylthiophen-2-yl)thieno[3,2-b]thiophene and 1,4-bis(dodecyloxy)-2,5-diethynylbenzene. Top contact OTFTs were fabricated by spin casting with 2 wt% solution of P1 in chloroform and their best performance, which exhibited a hole mobility of 4.5 × 10 -5 cm 2/Vs, was showed after annealing of the films at liquid crystalline temperature. Time-of-flight (TOF) mobility measured at liquid crystalline phase was observed to be 1.5 × 10 -6 cm 2/Vs for both positive and negative carriers. These results indicate that the liquid crystallinity helps to improve the molecular packing and enhance charge mobility for P1. These advantages can be applicable to design and construct solution-processable OTFT materials for electronic applications.

    Original languageEnglish
    Pages (from-to)6800-6804
    Number of pages5
    JournalJournal of nanoscience and nanotechnology
    Issue number10
    Publication statusPublished - Oct 1 2010

    All Science Journal Classification (ASJC) codes

    • Medicine(all)

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