Diffusion coefficients of cetyl alcohol in supercritical carbon dioxide

Hidenori Higashi, Yoshio Iwai, Tsuyoshi Oda, Kengo Murai, Yasuhiko Arai

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The diffusion coefficients of cetyl alcohol in supercritical carbon dioxide were measured by the pseudo steady state solid dissolution method at 308.2 K. The Schmidt number correlation was applied to correlate with the experimental diffusion coefficients. Further, molecular dynamics simulation was performed to calculate the diffusion coefficients by an all atom model of solute. The correlated results by the Schmidt number correlation show good agreement with the experimental results. The calculated results by molecular dynamics simulation give fair estimation to the experimental data without adjustable parameters.

Original languageEnglish
Pages (from-to)865-869
Number of pages5
JournalJOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Volume38
Issue number11
DOIs
Publication statusPublished - Nov 20 2005

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Carbon Dioxide
Carbon dioxide
Alcohols
Molecular dynamics
Computer simulation
Dissolution
Atoms
cetyl alcohol

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Diffusion coefficients of cetyl alcohol in supercritical carbon dioxide. / Higashi, Hidenori; Iwai, Yoshio; Oda, Tsuyoshi; Murai, Kengo; Arai, Yasuhiko.

In: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 38, No. 11, 20.11.2005, p. 865-869.

Research output: Contribution to journalArticle

Higashi, Hidenori ; Iwai, Yoshio ; Oda, Tsuyoshi ; Murai, Kengo ; Arai, Yasuhiko. / Diffusion coefficients of cetyl alcohol in supercritical carbon dioxide. In: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN. 2005 ; Vol. 38, No. 11. pp. 865-869.
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