Diffusion coefficients of naphthalene and dimethylnaphthalene in supercritical carbon dioxide

Hidenori Higashi, Yoshio Iwai, Yuichi Takahashi, Hirohisa Uchida, Yasuhiko Arai

Research output: Contribution to journalConference article

40 Citations (Scopus)

Abstract

A new experimental apparatus based on a pseudo-steady state solid dissolution method has been designed to measure the diffusion coefficients of supercritical carbon dioxide(1)-naphthalene(2) and supercritical carbon dioxide(1)-dimethylnaphthalene isomers(2) systems. The diffusion coefficients were measured at 308.2 K. In order to establish the validity of this method and the performance of the apparatus, the experimental results of the diffusion coefficients of naphthalene in supercritical carbon dioxide were compared with the literature data measured by other methods. The decrease of diffusion coefficient of naphthalene was observed near the critical point of carbon dioxide. The diffusion coefficients of 2,6-dimethylnaphthalene (2,6-DMN) and 2,7-dimethylnaphthalene (2,7-DMN) show almost the same values. The diffusion coefficients of these isomers are about 10% lower than those of naphthalene.

Original languageEnglish
Pages (from-to)269-278
Number of pages10
JournalFluid Phase Equilibria
Volume144
Issue number1-2
DOIs
Publication statusPublished - Feb 1 1998
EventProceedings of the 1997 2nd International Symposium on Molecular Thermodynamics and Molecular Simulation, MTMS'97 - Tokyo, Jpn
Duration: Jan 12 1997Jan 15 1997

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Naphthalene
naphthalene
Carbon Dioxide
carbon dioxide
Carbon dioxide
diffusion coefficient
Isomers
isomers
critical point
dissolving
Dissolution

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Diffusion coefficients of naphthalene and dimethylnaphthalene in supercritical carbon dioxide. / Higashi, Hidenori; Iwai, Yoshio; Takahashi, Yuichi; Uchida, Hirohisa; Arai, Yasuhiko.

In: Fluid Phase Equilibria, Vol. 144, No. 1-2, 01.02.1998, p. 269-278.

Research output: Contribution to journalConference article

Higashi, Hidenori ; Iwai, Yoshio ; Takahashi, Yuichi ; Uchida, Hirohisa ; Arai, Yasuhiko. / Diffusion coefficients of naphthalene and dimethylnaphthalene in supercritical carbon dioxide. In: Fluid Phase Equilibria. 1998 ; Vol. 144, No. 1-2. pp. 269-278.
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