Dimethoxyphenylpropyl bonded silica phase for higher fullerenes separation by high-performance liquid chromatography

Kiyokatsu Jinno; Hatsuichi Ohta; Yoshihiro Saito; Takashi Uemura; Hideo Nagashima; Kenji Itoh; Yung Lin Chen; Gary Luehr; Jim Archer; John C. Fetzer; Wilton R. Biggs

doi:10.1016/0021-9673(93)83288-4

Dimethoxyphenylpropyl bonded silica phase for higher fullerenes separation by high-performance liquid chromatography

Kiyokatsu Jinno, Hatsuichi Ohta, Yoshihiro Saito, Takashi Uemura, Hideo Nagashima, Kenji Itoh, Yung Lin Chen, Gary Luehr, Jim Archer, John C. Fetzer, Wilton R. Biggs

Research output: Contribution to journal › Article

33 Citations (Scopus)

Abstract

Fullerenes were separated using three chemically bonded phases, dimethoxyphenylpropyl (DMP), monomeric octadecyl and polymeric octadecyl modified silicas (ODS), with n-hexane as the mobile phase. DMP and the monomeric ODS are the best choices for the separation of C₆₀ and C₇₀ compounds, while DMP is the only phase that has high temperature stability while maintaining the resolution. For the separation of higher fullerenes, DMP offers faster analysis at higher temperatures while maintaining its high resolution, whereas ODS phases cannot provide similar run times while offering the same resolution. In conclusion, DMP is the most suitable and promising stationary phase for fullerenes analysis because of the short run time and its superior separation efficiency.

Original language	English
Pages (from-to)	71-77
Number of pages	7
Journal	Journal of Chromatography A
Volume	648
Issue number	1
DOIs	https://doi.org/10.1016/0021-9673(93)83288-4
Publication status	Published - Oct 1 1993
Externally published	Yes

All Science Journal Classification (ASJC) codes

Analytical Chemistry
Biochemistry
Organic Chemistry

Access to Document

10.1016/0021-9673(93)83288-4

Fingerprint Dive into the research topics of 'Dimethoxyphenylpropyl bonded silica phase for higher fullerenes separation by high-performance liquid chromatography'. Together they form a unique fingerprint.

Cite this

Jinno, K., Ohta, H., Saito, Y., Uemura, T., Nagashima, H., Itoh, K., Chen, Y. L., Luehr, G., Archer, J., Fetzer, J. C., & Biggs, W. R. (1993). Dimethoxyphenylpropyl bonded silica phase for higher fullerenes separation by high-performance liquid chromatography. Journal of Chromatography A, 648(1), 71-77. https://doi.org/10.1016/0021-9673(93)83288-4

Dimethoxyphenylpropyl bonded silica phase for higher fullerenes separation by high-performance liquid chromatography. / Jinno, Kiyokatsu; Ohta, Hatsuichi; Saito, Yoshihiro; Uemura, Takashi; Nagashima, Hideo; Itoh, Kenji; Chen, Yung Lin; Luehr, Gary; Archer, Jim; Fetzer, John C.; Biggs, Wilton R.

In: Journal of Chromatography A, Vol. 648, No. 1, 01.10.1993, p. 71-77.

Research output: Contribution to journal › Article

Jinno, Kiyokatsu ; Ohta, Hatsuichi ; Saito, Yoshihiro ; Uemura, Takashi ; Nagashima, Hideo ; Itoh, Kenji ; Chen, Yung Lin ; Luehr, Gary ; Archer, Jim ; Fetzer, John C. ; Biggs, Wilton R. / Dimethoxyphenylpropyl bonded silica phase for higher fullerenes separation by high-performance liquid chromatography. In: Journal of Chromatography A. 1993 ; Vol. 648, No. 1. pp. 71-77.

@article{882cedc9611742e9bb9540659d22c9f9,

title = "Dimethoxyphenylpropyl bonded silica phase for higher fullerenes separation by high-performance liquid chromatography",

abstract = "Fullerenes were separated using three chemically bonded phases, dimethoxyphenylpropyl (DMP), monomeric octadecyl and polymeric octadecyl modified silicas (ODS), with n-hexane as the mobile phase. DMP and the monomeric ODS are the best choices for the separation of C60 and C70 compounds, while DMP is the only phase that has high temperature stability while maintaining the resolution. For the separation of higher fullerenes, DMP offers faster analysis at higher temperatures while maintaining its high resolution, whereas ODS phases cannot provide similar run times while offering the same resolution. In conclusion, DMP is the most suitable and promising stationary phase for fullerenes analysis because of the short run time and its superior separation efficiency.",

author = "Kiyokatsu Jinno and Hatsuichi Ohta and Yoshihiro Saito and Takashi Uemura and Hideo Nagashima and Kenji Itoh and Chen, {Yung Lin} and Gary Luehr and Jim Archer and Fetzer, {John C.} and Biggs, {Wilton R.}",

year = "1993",

month = oct,

day = "1",

doi = "10.1016/0021-9673(93)83288-4",

language = "English",

volume = "648",

pages = "71--77",

journal = "Journal of Chromatography",

issn = "0021-9673",

publisher = "Elsevier",

number = "1",

}

TY - JOUR

T1 - Dimethoxyphenylpropyl bonded silica phase for higher fullerenes separation by high-performance liquid chromatography

AU - Jinno, Kiyokatsu

AU - Ohta, Hatsuichi

AU - Saito, Yoshihiro

AU - Uemura, Takashi

AU - Nagashima, Hideo

AU - Itoh, Kenji

AU - Chen, Yung Lin

AU - Luehr, Gary

AU - Archer, Jim

AU - Fetzer, John C.

AU - Biggs, Wilton R.

PY - 1993/10/1

Y1 - 1993/10/1

N2 - Fullerenes were separated using three chemically bonded phases, dimethoxyphenylpropyl (DMP), monomeric octadecyl and polymeric octadecyl modified silicas (ODS), with n-hexane as the mobile phase. DMP and the monomeric ODS are the best choices for the separation of C60 and C70 compounds, while DMP is the only phase that has high temperature stability while maintaining the resolution. For the separation of higher fullerenes, DMP offers faster analysis at higher temperatures while maintaining its high resolution, whereas ODS phases cannot provide similar run times while offering the same resolution. In conclusion, DMP is the most suitable and promising stationary phase for fullerenes analysis because of the short run time and its superior separation efficiency.

AB - Fullerenes were separated using three chemically bonded phases, dimethoxyphenylpropyl (DMP), monomeric octadecyl and polymeric octadecyl modified silicas (ODS), with n-hexane as the mobile phase. DMP and the monomeric ODS are the best choices for the separation of C60 and C70 compounds, while DMP is the only phase that has high temperature stability while maintaining the resolution. For the separation of higher fullerenes, DMP offers faster analysis at higher temperatures while maintaining its high resolution, whereas ODS phases cannot provide similar run times while offering the same resolution. In conclusion, DMP is the most suitable and promising stationary phase for fullerenes analysis because of the short run time and its superior separation efficiency.

UR - http://www.scopus.com/inward/record.url?scp=0027366467&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0027366467&partnerID=8YFLogxK

U2 - 10.1016/0021-9673(93)83288-4

DO - 10.1016/0021-9673(93)83288-4

M3 - Article

AN - SCOPUS:0027366467

VL - 648

SP - 71

EP - 77

JO - Journal of Chromatography

JF - Journal of Chromatography

SN - 0021-9673

IS - 1

ER -