Direct fabrication of crystallized LiCoO2 films on paper by artificial biomineralization with electrochemically activated interfacial reactions

Takeshi Fujiwara, Yoshinori Nakagaw, Takuya Nakaue, Seung Wan Song, Tomoaki Watanabe, Ryo Teranishi, Masahiro Yoshimura

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

We have developed a new method to directly fabricate lithium cobalt oxide (LiCoO2) films onto porous films by an electrodeposition method in solutions at low temperature. A set of porous substrate films consisting of a PTFE membrane-filter and paper was placed between a LiOH solution and a CoSO4 solution. Cobalt compounds were deposited on the substrates under electrical currents of ∼1 mA/cm2 using carbon electrodes. As a result, we found that LiCoO2 films on the porous filter were successfully fabricated at 120 °C. Furthermore, the LiCoO2 films did not cover the entire substrate, but formed only in the shape of the anode.

Original languageEnglish
Pages (from-to)369-373
Number of pages5
JournalChemical Physics Letters
Volume365
Issue number5-6
DOIs
Publication statusPublished - Nov 13 2002
Externally publishedYes

Fingerprint

Biomineralization
Surface chemistry
Fabrication
fabrication
Substrates
Cobalt compounds
cobalt compounds
filters
lithium oxides
cobalt oxides
Polytetrafluoroethylene
Electrodeposition
electrodeposition
Oxide films
oxide films
Anodes
anodes
Carbon
membranes
Membranes

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Direct fabrication of crystallized LiCoO2 films on paper by artificial biomineralization with electrochemically activated interfacial reactions. / Fujiwara, Takeshi; Nakagaw, Yoshinori; Nakaue, Takuya; Song, Seung Wan; Watanabe, Tomoaki; Teranishi, Ryo; Yoshimura, Masahiro.

In: Chemical Physics Letters, Vol. 365, No. 5-6, 13.11.2002, p. 369-373.

Research output: Contribution to journalArticle

Fujiwara, Takeshi ; Nakagaw, Yoshinori ; Nakaue, Takuya ; Song, Seung Wan ; Watanabe, Tomoaki ; Teranishi, Ryo ; Yoshimura, Masahiro. / Direct fabrication of crystallized LiCoO2 films on paper by artificial biomineralization with electrochemically activated interfacial reactions. In: Chemical Physics Letters. 2002 ; Vol. 365, No. 5-6. pp. 369-373.
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