Direct Hydrophilic Modification of Polymer Surfaces via Surface-Initiated ATRP

Yuji Higaki, Motoyasu Kobayashi, Atsushi Takahara

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Various hydrophilic modification approaches for solid polymer articles have been proposed. However, most methods scarcely ensure the long-term stability of the hydrophilicity due to the surface reorganization. The direct surface modification of polymer fibers and films by surface-initiated atom transfer radical polymerization (SI-ATRP) of charged monomers was investigated to achieve the stable surface modification of polymer articles. 2-(Methacryloyloxy)ethyl phosphorylcholine (MPC) was polymerized in the presence of compression molded sheets of bromo-functionalized polyethylene or polypropylene macroinitiators under mild conditions to provide a superhydrophilic PMPC-grafted surface layer. The PMPC-grafted polyolefin sheets showed excellent wettability and oil-detachment behavior in water. The PMPC-grafted PP sheets retained a water contact angle of less than 10° for over three years in air. A facile surface modification procedure for electrospun poly(butylene terephthalate) (PBT) fibers by SI-ATRP was proposed. ATRP initiators were introduced on the surface of the PBT fibers through aminolysis and subsequent chemical vapor adsorption. Poly[3-(N-2-methacryloyloxyethyl-N,N-dimethyl)ammonatopropanesulfonate)] (PMAPS) was grafted to the PBT fibers via SI-ATRP without altering the fiber geometry. After modification with zwitterionic poly(sulfobetaine) brushes, the surface became superhydrophilic. The surface properties were thermally stable due to the high melting temperature of the PBT crystallites, and were maintained for a prolonged period.

Original languageEnglish
Title of host publicationReversible Deactivation Radical Polymerization
Subtitle of host publicationMaterials and Applications
EditorsKrzysztof Matyjaszewski, Haifeng Gao, Nicolay V. Tsarevsky, Brent S. Sumerlin
PublisherAmerican Chemical Society
Pages157-168
Number of pages12
ISBN (Print)9780841233232
DOIs
Publication statusPublished - Jan 1 2018

Publication series

NameACS Symposium Series
Volume1285
ISSN (Print)0097-6156
ISSN (Electronic)1947-5918

Fingerprint

Atom transfer radical polymerization
Polymers
Fibers
Surface treatment
Phosphorylcholine
Water
Polypropylenes
Polyolefins
Hydrophilicity
Polyethylene
Brushes
Crystallites
Contact angle
Surface properties
Melting point
Wetting
Polyethylenes
Oils
Monomers
Vapors

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Higaki, Y., Kobayashi, M., & Takahara, A. (2018). Direct Hydrophilic Modification of Polymer Surfaces via Surface-Initiated ATRP. In K. Matyjaszewski, H. Gao, N. V. Tsarevsky, & B. S. Sumerlin (Eds.), Reversible Deactivation Radical Polymerization: Materials and Applications (pp. 157-168). (ACS Symposium Series; Vol. 1285). American Chemical Society. https://doi.org/10.1021/bk-2018-1285.ch009

Direct Hydrophilic Modification of Polymer Surfaces via Surface-Initiated ATRP. / Higaki, Yuji; Kobayashi, Motoyasu; Takahara, Atsushi.

Reversible Deactivation Radical Polymerization: Materials and Applications. ed. / Krzysztof Matyjaszewski; Haifeng Gao; Nicolay V. Tsarevsky; Brent S. Sumerlin. American Chemical Society, 2018. p. 157-168 (ACS Symposium Series; Vol. 1285).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Higaki, Y, Kobayashi, M & Takahara, A 2018, Direct Hydrophilic Modification of Polymer Surfaces via Surface-Initiated ATRP. in K Matyjaszewski, H Gao, NV Tsarevsky & BS Sumerlin (eds), Reversible Deactivation Radical Polymerization: Materials and Applications. ACS Symposium Series, vol. 1285, American Chemical Society, pp. 157-168. https://doi.org/10.1021/bk-2018-1285.ch009
Higaki Y, Kobayashi M, Takahara A. Direct Hydrophilic Modification of Polymer Surfaces via Surface-Initiated ATRP. In Matyjaszewski K, Gao H, Tsarevsky NV, Sumerlin BS, editors, Reversible Deactivation Radical Polymerization: Materials and Applications. American Chemical Society. 2018. p. 157-168. (ACS Symposium Series). https://doi.org/10.1021/bk-2018-1285.ch009
Higaki, Yuji ; Kobayashi, Motoyasu ; Takahara, Atsushi. / Direct Hydrophilic Modification of Polymer Surfaces via Surface-Initiated ATRP. Reversible Deactivation Radical Polymerization: Materials and Applications. editor / Krzysztof Matyjaszewski ; Haifeng Gao ; Nicolay V. Tsarevsky ; Brent S. Sumerlin. American Chemical Society, 2018. pp. 157-168 (ACS Symposium Series).
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