Direct substitution of the hydroxy group with highly functionalized nitrogen nucleophiles catalyzed by Au(III)

Takashi Ohshima, Yasuhito Nakahara, Junji Ipposhi, Yoshiki Miyamoto, Kazushi Mashima

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

A direct catalytic substitution of various allylic and benzylic alcohols with synthetically useful, but acid-sensitive Boc, Bus, and Dios protected amine nucleophiles, which have not been well utilized for Lewis acid catalysis, with various functionalities (OTBS, OTHP, etc.) was efficiently catalyzed by 1 mol% of Au(iii) under mild conditions.

Original languageEnglish
Pages (from-to)8322-8324
Number of pages3
JournalChemical Communications
Volume47
Issue number29
DOIs
Publication statusPublished - Aug 7 2011

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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