Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation

Suguru Yoshida, Takahisa Yano, Yoshihiro Misawa, Yasuyuki Sugimura, Kazunobu Igawa, Shigeomi Shimizu, Katsuhiko Tomooka, Takamitsu Hosoya

Research output: Contribution to journalArticlepeer-review

80 Citations (Scopus)

Abstract

A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C-N and C-S bond formations and migratory N-arylation.

Original languageEnglish
Pages (from-to)14071-14074
Number of pages4
JournalJournal of the American Chemical Society
Volume137
Issue number44
DOIs
Publication statusPublished - Nov 11 2015

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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