TY - JOUR
T1 - Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands
AU - Kuriyama, Shogo
AU - Arashiba, Kazuya
AU - Tanaka, Hiromasa
AU - Matsuo, Yuki
AU - Nakajima, Kazunari
AU - Yoshizawa, Kazunari
AU - Nishibayashi, Yoshiaki
N1 - Funding Information:
The present project was supported by CREST, JST, and the Mitsubishi Foundation. We acknowledge Grants-in-Aid for Scientific Research (JP26288044, JP26105708, JP15K13687, and JP15H05798 to Y.N., JP24109014 to K.Y., and JP26888008 to H.T.) from the JSPS and MEXT. S.K. is the recipient of a JSPS Predoctoral Fellowship for Young Scientists.
Publisher Copyright:
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2016/11/7
Y1 - 2016/11/7
N2 - The direct formation of ammonia from molecular dinitrogen under mild reaction conditions was achieved by using new cobalt dinitrogen complexes bearing an anionic PNP-type pincer ligand. Up to 15.9 equivalents of ammonia were produced based on the amount of catalyst together with 1.0 equivalent of hydrazine (17.9 equiv of fixed nitrogen atoms).
AB - The direct formation of ammonia from molecular dinitrogen under mild reaction conditions was achieved by using new cobalt dinitrogen complexes bearing an anionic PNP-type pincer ligand. Up to 15.9 equivalents of ammonia were produced based on the amount of catalyst together with 1.0 equivalent of hydrazine (17.9 equiv of fixed nitrogen atoms).
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U2 - 10.1002/anie.201606090
DO - 10.1002/anie.201606090
M3 - Article
AN - SCOPUS:84981712781
SN - 1433-7851
VL - 55
SP - 14291
EP - 14295
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 46
ER -