Disilaferracycle dicarbonyl complex containing weakly coordinated η2-(H-Si) ligands

Application to C-H functionalization of indoles and arenes

Yusuke Sunada, Hiroe Soejima, Hideo Nagashima

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

Well-defined iron complex-mediated catalytic C-3-selective silylation of indole derivatives and stoichiometric C-H bond functionalization of arenes were achieved using an iron dicarbonyl complex containing the disilaferracycle moiety [o-(SiMe2)2C6H4]Fe(CO)2[o-{η2-(H-SiMe2)2}C6H4] (1). Facile liberation of the η2-(H-Si) groups in 1 was the key to effective promotion of these reactions.

Original languageEnglish
Pages (from-to)5936-5939
Number of pages4
JournalOrganometallics
Volume33
Issue number21
DOIs
Publication statusPublished - Nov 10 2014

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Indoles
indoles
Iron
Ligands
iron
ligands
promotion
Carbon Monoxide
Derivatives
indole

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Disilaferracycle dicarbonyl complex containing weakly coordinated η2-(H-Si) ligands : Application to C-H functionalization of indoles and arenes. / Sunada, Yusuke; Soejima, Hiroe; Nagashima, Hideo.

In: Organometallics, Vol. 33, No. 21, 10.11.2014, p. 5936-5939.

Research output: Contribution to journalArticle

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