Dissolved N2 sensing by pH-dependent Ru complexes

Tetsuro Kizaki, Takahiro Matsumoto, Seiji Ogo

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

This paper describes the synthesis and characterisation of Ru-based, water-soluble complexes [RuII(X)(Y)(TMC)] (X, Y = H2O or OH; TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) capable of behaving as colorimetric, water-soluble, dissolved N2 sensors. Unlike previous water-soluble N2 complexes, binding to N2 is both reversible and pH-switchable, i.e., binding can be switched on at high pHs and switched off at low pHs. Sensing can be performed at partial pressures of N2 as low as 0.01 MPa.

Original languageEnglish
Pages (from-to)1339-1344
Number of pages6
JournalDalton Transactions
Volume39
Issue number5
DOIs
Publication statusPublished - Feb 22 2010

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All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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