Distance-depending photoinduced electron transfer at two-dimensional interface in alternate stacked structures of tantalate nanosheets and tungstate nanosheets

Taishi Ano, Fuminao Kishimoto, Dai Mochizuki, Shuntaro Tsubaki, Masato M. Maitani, Eiichi Suzuki, Yuji Wada

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

We demonstrate the electron transfer from the conduction band of tantalate nanosheets to that of tungstate nanosheets depending on the interlayer distance in the alternate-stacked structure prepared by the thiol-ene click reaction of thiol-grafted tantalate nanosheets and alkene-grafted tungstate nanosheets. The interlayer distance is precisely controlled from 0.93 to 1.64 nm by changing the methylene chain number of the organic bridges. The logarithm of the rate constant of the electron transfer decreases linearly with the distance.

Original languageEnglish
Pages (from-to)1111-1113
Number of pages3
JournalChemistry Letters
Volume45
Issue number9
DOIs
Publication statusPublished - 2016
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Fingerprint

Dive into the research topics of 'Distance-depending photoinduced electron transfer at two-dimensional interface in alternate stacked structures of tantalate nanosheets and tungstate nanosheets'. Together they form a unique fingerprint.

Cite this