Distribution and solubility limit of AI in Al2O 3-doped ZnO sintered body

Keita Shirouzu, Takahiro Ohkusa, Mikinori Hotta, Naoya Enomoto, Junichi Hojo

    Research output: Contribution to journalArticlepeer-review

    68 Citations (Scopus)

    Abstract

    A few mol% Al2O3-doped ZnO sintered body forms a substitutional solid solution and the semi-conducting property is drastically affected by the content of the dissolved AI. It was suggested from the results of XRD and EPMA that Al existed in the ZnO sintered body in the form of ZnAl2O4. Furthermore, the distribution of ZnAl 2O4 was visualized by AFM and SEM. It was, however, difficult for these techniques to detect dissolved Al in ZnO grains directly. The SIMS mapping suggested that the trace amount of Al (approximately 0.3 atomic%) dissolved into ZnO grains because of high sensitivity for trace impurities. This result was consistent with the change in lattice constants of ZnO with Al dissolution.

    Original languageEnglish
    Pages (from-to)254-258
    Number of pages5
    JournalJournal of the Ceramic Society of Japan
    Volume115
    Issue number1340
    DOIs
    Publication statusPublished - Apr 2007

    All Science Journal Classification (ASJC) codes

    • Ceramics and Composites
    • Chemistry(all)
    • Condensed Matter Physics
    • Materials Chemistry

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