Donor-Acceptor-Collector Ternary Crystalline Films for Efficient Solid-State Photon Upconversion

Taku Ogawa, Masanori Hosoyamada, Brett Yurash, Thuc Quyen Nguyen, Nobuhiro Yanai, Nobuo Kimizuka

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

It is pivotal to achieve efficient triplet-triplet annihilation based photon upconversion (TTA-UC) in the solid-state for enhancing potentials of renewable energy production devices. However, the UC efficiency of solid materials is largely limited by low fluorescence quantum yields that originate from the aggregation of TTA-UC chromophores and also by severe back energy transfer from the acceptor singlet state to the singlet state of the triplet donor in the condensed state. In this work, to overcome these issues, we introduce a highly fluorescent singlet energy collector as the third component of donor-doped acceptor crystalline films, in which dual energy migration, i.e., triplet energy migration for TTA-UC and succeeding singlet energy migration for transferring energy to a collector, takes place. To demonstrate this scheme, a highly fluorescent singlet energy collector was added as the third component of donor-doped acceptor crystalline films. An anthracene-based acceptor containing alkyl chains and a carboxylic moiety is mixed with the triplet donor Pt(II) octaethylporphyrin (PtOEP) and the energy collector 2,5,8,11-tetra-tert-butylperylene (TTBP) in solution, and simple spin-coating of the mixed solution gives acceptor films of nanofibrous crystals homogeneously doped with PtOEP and TTBP. Interestingly, delocalized singlet excitons in acceptor crystals are found to diffuse effectively over the distance of ∼37 nm. Thanks to this high diffusivity, only 0.5 mol % of doped TTBP can harvest most of the singlet excitons, which successfully doubles the solid-state fluorescent quantum yield of acceptor/TTBP blend films to 76%. Furthermore, since the donor PtOEP and the collector TTBP are separately isolated in the nanofibrous acceptor crystals, the singlet back energy transfer from the collector to the donor is effectively avoided. Such efficient singlet energy collection and inhibited back energy transfer processes result in a large increase of UC efficiency up to 9.0%, offering rational design principles toward ultimately efficient solid-state upconverters.

Original languageEnglish
Pages (from-to)8788-8796
Number of pages9
JournalJournal of the American Chemical Society
Volume140
Issue number28
DOIs
Publication statusPublished - Jul 18 2018

Fingerprint

Energy Transfer
Photons
Energy transfer
Crystalline materials
Quantum yield
Excitons
Renewable Energy
Crystals
Anthracene
Spin coating
Chromophores
Fluorescence
Equipment and Supplies
Agglomeration
octaethylporphyrin
LDS 751

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Donor-Acceptor-Collector Ternary Crystalline Films for Efficient Solid-State Photon Upconversion. / Ogawa, Taku; Hosoyamada, Masanori; Yurash, Brett; Nguyen, Thuc Quyen; Yanai, Nobuhiro; Kimizuka, Nobuo.

In: Journal of the American Chemical Society, Vol. 140, No. 28, 18.07.2018, p. 8788-8796.

Research output: Contribution to journalArticle

Ogawa, Taku ; Hosoyamada, Masanori ; Yurash, Brett ; Nguyen, Thuc Quyen ; Yanai, Nobuhiro ; Kimizuka, Nobuo. / Donor-Acceptor-Collector Ternary Crystalline Films for Efficient Solid-State Photon Upconversion. In: Journal of the American Chemical Society. 2018 ; Vol. 140, No. 28. pp. 8788-8796.
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