Double-decker ferrocene-type complex of N-fused porphyrin: A model of π-extended ferrocene?

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Whopper sandwich: A double-decker ferrocene-type complex with N-fused porphyrinato ligands (see picture) was synthesized from N-fused porphyrin, and its structure and properties were characterized with X-ray crystallographic analysis, variable-temperature 1H NMR spectra, and electrochemical measurements. The unique three-dimensional d-π conjugated system was elucidated with the aid of DFT studies.

Original languageEnglish
Pages (from-to)2752-2755
Number of pages4
JournalAngewandte Chemie - International Edition
Volume50
Issue number12
DOIs
Publication statusPublished - Mar 14 2011

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Porphyrins
Discrete Fourier transforms
Ligands
Nuclear magnetic resonance
X rays
Temperature
ferrocene

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Double-decker ferrocene-type complex of N-fused porphyrin : A model of π-extended ferrocene? / Toganoh, Motoki; Sato, Ayumi; Furuta, Hiroyuki.

In: Angewandte Chemie - International Edition, Vol. 50, No. 12, 14.03.2011, p. 2752-2755.

Research output: Contribution to journalArticle

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