Double-decker ferrocene-type complex of N-fused porphyrin: A model of π-extended ferrocene?

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    Abstract

    Whopper sandwich: A double-decker ferrocene-type complex with N-fused porphyrinato ligands (see picture) was synthesized from N-fused porphyrin, and its structure and properties were characterized with X-ray crystallographic analysis, variable-temperature 1H NMR spectra, and electrochemical measurements. The unique three-dimensional d-π conjugated system was elucidated with the aid of DFT studies.

    Original languageEnglish
    Pages (from-to)2752-2755
    Number of pages4
    JournalAngewandte Chemie - International Edition
    Volume50
    Issue number12
    DOIs
    Publication statusPublished - Mar 14 2011

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Chemistry(all)

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