Double-layered honeycomb architectures constructedviahierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles

Ryohei Akiyoshi; Keita Kuroiwa; Mina Sakuragi; Soichiro Yoshimoto; Ryo Ohtani; Masaaki Nakamura; Leonard F. Lindoy; Shinya Hayami

doi:10.1039/d0cc02628j

Double-layered honeycomb architectures constructedviahierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles

Ryohei Akiyoshi, Keita Kuroiwa, Mina Sakuragi, Soichiro Yoshimoto, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami

Research output: Contribution to journal › Article

Abstract

A hexagonal cobalt(ii) metallacycle and its “lipid packaged” derivatives, [Co₆(R-bisterpy)₆]X₁₂(R = H, OC₁₆H₃₃, OC₂₇H₅₅; X = BF₄, C₁₂-Glu), have been synthesized and characterized. The compounds incorporating BF₄^-anions formed sphere-like aggregates while the compounds with C₁₂-Glu lipid anions gave double-layered honeycomb architectures composed of hexagonal stacked tubular structures, which exhibit spin crossover behaviour.

Original language	English
Pages (from-to)	5835-5838
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	43
DOIs	https://doi.org/10.1039/d0cc02628j
Publication status	Published - May 28 2020
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d0cc02628j

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Akiyoshi, R., Kuroiwa, K., Sakuragi, M., Yoshimoto, S., Ohtani, R., Nakamura, M., Lindoy, L. F., & Hayami, S. (2020). Double-layered honeycomb architectures constructedviahierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles. Chemical Communications, 56(43), 5835-5838. https://doi.org/10.1039/d0cc02628j

Double-layered honeycomb architectures constructedviahierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles. / Akiyoshi, Ryohei; Kuroiwa, Keita; Sakuragi, Mina; Yoshimoto, Soichiro; Ohtani, Ryo; Nakamura, Masaaki; Lindoy, Leonard F.; Hayami, Shinya.

In: Chemical Communications, Vol. 56, No. 43, 28.05.2020, p. 5835-5838.

Research output: Contribution to journal › Article

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abstract = "A hexagonal cobalt(ii) metallacycle and its “lipid packaged” derivatives, [Co6(R-bisterpy)6]X12(R = H, OC16H33, OC27H55; X = BF4, C12-Glu), have been synthesized and characterized. The compounds incorporating BF4-anions formed sphere-like aggregates while the compounds with C12-Glu lipid anions gave double-layered honeycomb architectures composed of hexagonal stacked tubular structures, which exhibit spin crossover behaviour.",

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AU - Ohtani, Ryo

AU - Nakamura, Masaaki

AU - Lindoy, Leonard F.

AU - Hayami, Shinya

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