Double-layered honeycomb architectures constructedviahierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles

Ryohei Akiyoshi; Keita Kuroiwa; Mina Sakuragi; Soichiro Yoshimoto; Ryo Ohtani; Masaaki Nakamura; Leonard F. Lindoy; Shinya Hayami

doi:10.1039/d0cc02628j

Double-layered honeycomb architectures constructedviahierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles

Ryohei Akiyoshi, Keita Kuroiwa, Mina Sakuragi, Soichiro Yoshimoto, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A hexagonal cobalt(ii) metallacycle and its “lipid packaged” derivatives, [Co₆(R-bisterpy)₆]X₁₂(R = H, OC₁₆H₃₃, OC₂₇H₅₅; X = BF₄, C₁₂-Glu), have been synthesized and characterized. The compounds incorporating BF₄^-anions formed sphere-like aggregates while the compounds with C₁₂-Glu lipid anions gave double-layered honeycomb architectures composed of hexagonal stacked tubular structures, which exhibit spin crossover behaviour.

Original language	English
Pages (from-to)	5835-5838
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	43
DOIs	https://doi.org/10.1039/d0cc02628j
Publication status	Published - May 28 2020
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d0cc02628j

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@article{7d94353101a54abc8ba82243521f17cc,

title = "Double-layered honeycomb architectures constructedviahierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles",

abstract = "A hexagonal cobalt(ii) metallacycle and its “lipid packaged” derivatives, [Co6(R-bisterpy)6]X12(R = H, OC16H33, OC27H55; X = BF4, C12-Glu), have been synthesized and characterized. The compounds incorporating BF4-anions formed sphere-like aggregates while the compounds with C12-Glu lipid anions gave double-layered honeycomb architectures composed of hexagonal stacked tubular structures, which exhibit spin crossover behaviour.",

author = "Ryohei Akiyoshi and Keita Kuroiwa and Mina Sakuragi and Soichiro Yoshimoto and Ryo Ohtani and Masaaki Nakamura and Lindoy, {Leonard F.} and Shinya Hayami",

note = "Funding Information: This work was supported by KAKENHI Grant-in-Aid for Scientific Research (A) JP17H01200. This work was partially supported by SPring-8 BL40B2 (2018B1424) and Kyushu Synchrotron Light Research Centre BL11 (1807056F). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2020. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2020",

month = may,

day = "28",

doi = "10.1039/d0cc02628j",

language = "English",

volume = "56",

pages = "5835--5838",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "43",

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TY - JOUR

T1 - Double-layered honeycomb architectures constructedviahierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles

AU - Akiyoshi, Ryohei

AU - Kuroiwa, Keita

AU - Sakuragi, Mina

AU - Yoshimoto, Soichiro

AU - Ohtani, Ryo

AU - Nakamura, Masaaki

AU - Lindoy, Leonard F.

AU - Hayami, Shinya

N1 - Funding Information: This work was supported by KAKENHI Grant-in-Aid for Scientific Research (A) JP17H01200. This work was partially supported by SPring-8 BL40B2 (2018B1424) and Kyushu Synchrotron Light Research Centre BL11 (1807056F). Publisher Copyright: © The Royal Society of Chemistry 2020. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/5/28

Y1 - 2020/5/28

N2 - A hexagonal cobalt(ii) metallacycle and its “lipid packaged” derivatives, [Co6(R-bisterpy)6]X12(R = H, OC16H33, OC27H55; X = BF4, C12-Glu), have been synthesized and characterized. The compounds incorporating BF4-anions formed sphere-like aggregates while the compounds with C12-Glu lipid anions gave double-layered honeycomb architectures composed of hexagonal stacked tubular structures, which exhibit spin crossover behaviour.

AB - A hexagonal cobalt(ii) metallacycle and its “lipid packaged” derivatives, [Co6(R-bisterpy)6]X12(R = H, OC16H33, OC27H55; X = BF4, C12-Glu), have been synthesized and characterized. The compounds incorporating BF4-anions formed sphere-like aggregates while the compounds with C12-Glu lipid anions gave double-layered honeycomb architectures composed of hexagonal stacked tubular structures, which exhibit spin crossover behaviour.

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

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ER -

Double-layered honeycomb architectures constructedviahierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles

Abstract

All Science Journal Classification (ASJC) codes

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