Abstract
A hexagonal cobalt(ii) metallacycle and its “lipid packaged” derivatives, [Co6(R-bisterpy)6]X12(R = H, OC16H33, OC27H55; X = BF4, C12-Glu), have been synthesized and characterized. The compounds incorporating BF4-anions formed sphere-like aggregates while the compounds with C12-Glu lipid anions gave double-layered honeycomb architectures composed of hexagonal stacked tubular structures, which exhibit spin crossover behaviour.
Original language | English |
---|---|
Pages (from-to) | 5835-5838 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 56 |
Issue number | 43 |
DOIs | |
Publication status | Published - May 28 2020 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry